Role of the intramolecular‐locking strategy in the construction of organic thermally activated delayed fluorescence emitters with rotation‐restricted acceptors
B Li, M Liu, L Sang, Z Li, X Wan… - Advanced Optical …, 2023 - Wiley Online Library
Constructing highly twisted and rigid donor–acceptor systems is important for obtaining
highly efficient thermally activated delayed fluorescence (TADF) emitters. In the traditional …
highly efficient thermally activated delayed fluorescence (TADF) emitters. In the traditional …
Chemical and conformational control of the energy gaps involved in the thermally activated delayed fluorescence mechanism
PL dos Santos, MK Etherington… - Journal of Materials …, 2018 - pubs.rsc.org
This review summarises the significant developments in our understanding and control of
thermally-activated delayed fluorescence (TADF) molecules and the spin–vibronic coupling …
thermally-activated delayed fluorescence (TADF) molecules and the spin–vibronic coupling …
Highly emissive excitons with reduced exchange energy in thermally activated delayed fluorescent molecules
Unlike conventional thermally activated delayed fluorescence chromophores, boron-
centered azatriangulene-like molecules combine a small excited-state singlet-triplet energy …
centered azatriangulene-like molecules combine a small excited-state singlet-triplet energy …
Regio-and conformational isomerization critical to design of efficient thermally-activated delayed fluorescence emitters
Regio-and conformational isomerization are fundamental in chemistry, with profound effects
upon physical properties, however their role in excited state properties is less developed …
upon physical properties, however their role in excited state properties is less developed …
Avoiding energy loss on TADF emitters: controlling the dual conformations of D–A structure molecules based on the pseudoplanar segments
The recent introduction of thermally activated delayed fluorescence (TADF) emitters is
regarded as an important breakthrough for the development of high efficiency organic light …
regarded as an important breakthrough for the development of high efficiency organic light …
Linearly Arranged Multi‐π‐Stacked Structure for Efficient Through‐Space Charge‐Transfer Emitters
Noncovalent spatial interaction has become an intriguing and important tool for constructing
optoelectronic molecules. In this study, we linearly attached three conjugated units in a multi …
optoelectronic molecules. In this study, we linearly attached three conjugated units in a multi …
Computational design of thermally activated delayed fluorescence materials: The challenges ahead
Y Olivier, JC Sancho-Garcia, L Muccioli… - The journal of …, 2018 - ACS Publications
Thermally activated delayed fluorescence (TADF) offers promise for all-organic light-emitting
diodes with quantum efficiencies competing with those of transition-metal-based …
diodes with quantum efficiencies competing with those of transition-metal-based …
Integrating molecular rigidity and chirality into thermally activated delayed fluorescence emitters for highly efficient sky-blue and orange circularly polarized …
F Ni, CW Huang, Y Tang, Z Chen, Y Wu, S Xia… - Materials …, 2021 - pubs.rsc.org
By integrating high molecular rigidity and stable chirality, two pairs of D*–A type circularly
polarized thermally activated delayed fluorescence (CP-TADF) emitters with an almost …
polarized thermally activated delayed fluorescence (CP-TADF) emitters with an almost …
Nature of the singlet and triplet excitations mediating thermally activated delayed fluorescence
Despite significant efforts, a complete mechanistic understanding of thermally activated
delayed fluorescence (TADF) materials has not yet been fully uncovered. Part of the …
delayed fluorescence (TADF) materials has not yet been fully uncovered. Part of the …
Electron spin resonance resolves intermediate triplet states in delayed fluorescence
Molecular organic fluorophores are currently used in organic light-emitting diodes, though
non-emissive triplet excitons generated in devices incorporating conventional fluorophores …
non-emissive triplet excitons generated in devices incorporating conventional fluorophores …