Carbenes and nitrenes: recent developments in fundamental chemistry
C Wentrup - Angewandte Chemie International Edition, 2018 - Wiley Online Library
Carbenes and nitrenes can exist in both singlet and triplet states, sometimes equally stable
and interconverting either thermally or photochemically. Many carbene and nitrene reactions …
and interconverting either thermally or photochemically. Many carbene and nitrene reactions …
[HTML][HTML] Design of magnetic organic molecules and organic magnets: experiment, theory and computation with application and recent advances
We begin by reviewing the early developments in the synthesis of high-spin organic
molecules and the simultaneous rationalization of the ground states of high spin. A number …
molecules and the simultaneous rationalization of the ground states of high spin. A number …
Electronic structures of aromatic hydrocarbons with high spin multiplicities in the electronic ground state
K Itoh - Pure and Applied Chemistry 26th, 1978 - degruyter.com
It has been established experimentally that there are alternant hydrocarbons (AH) with high
spin multiplicities in the electr~ pic ground state, the highest multiplicity known up to date …
spin multiplicities in the electr~ pic ground state, the highest multiplicity known up to date …
Nanoporous FePd alloy as multifunctional ferromagnetic SERS-active substrate
Nanoporous materials represent a unique class of materials, given to their unforeseen
magnetic, mechanical, optical and catalytic properties arising from their network of pores …
magnetic, mechanical, optical and catalytic properties arising from their network of pores …
Six-membered aromatic polyazides: Synthesis and application
SV Chapyshev - Molecules, 2015 - mdpi.com
Aromatic polyazides are widely used as starting materials in organic synthesis and
photochemical studies, as well as photoresists in microelectronics and as cross-linking …
photochemical studies, as well as photoresists in microelectronics and as cross-linking …
Molecular Magnets: The Synthesis and Characterization of High‐Spin Nitrenes
SV Chapyshev, E Mendez‐Vega… - Chemistry–A European …, 2021 - Wiley Online Library
Abstract Among all C‐, N‐, and O‐centered polyradicals, high‐spin nitrenes possess the
largest magnetic anisotropy and are of considerable interest as multi‐level molecular spin …
largest magnetic anisotropy and are of considerable interest as multi‐level molecular spin …
The EPR spectrum of triplet mesitylphosphinidene: Reassignment and new assignment
Low‐temperature UV‐photolysis of mesitylphosphiranes under highly anaerobic conditions
leads to the formation of the triplet mesitylphosphinidene (MesP). The recorded X‐band EPR …
leads to the formation of the triplet mesitylphosphinidene (MesP). The recorded X‐band EPR …
Recent advances in chemistry of high-spin nitrenes
SV Chapyshev, DV Korchagin… - Russian Chemical …, 2021 - iopscience.iop.org
Experimental and theoretical studies on aromatic nitrenes bearing from three to six unpaired
electrons and having quartet, quintet, sextet or septet ground spin states, published in the …
electrons and having quartet, quintet, sextet or septet ground spin states, published in the …
W-band EPR studies of high-spin nitrenes with large spin-orbit contribution to zero-field splitting
A Akimov, A Masitov, D Korchagin… - The Journal of …, 2015 - pubs.aip.org
First W-band 94 GHz EPR spectra of randomly oriented triplet, quintet, and septet nitrenes
formed during the photolysis of 1, 3, 5-triazido-2, 4, 6-tribromobenzene in cryogenic matrices …
formed during the photolysis of 1, 3, 5-triazido-2, 4, 6-tribromobenzene in cryogenic matrices …
The powder X‐band electron paramagnetic resonance spectroscopy of septet pyridyl‐2, 4, 6‐trinitrene
SV Chapyshev, DV Korchagin, P Costa… - Magnetic Resonance …, 2022 - Wiley Online Library
The first X‐band EPR spectrum containing only non‐overlapping signals of septet pyridyl‐2,
4, 6‐trinitrene and triplet pyridylnitrenes is reported. This spectrum was recorded after …
4, 6‐trinitrene and triplet pyridylnitrenes is reported. This spectrum was recorded after …