Atomically precise alloy nanoclusters: syntheses, structures, and properties

X Kang, Y Li, M Zhu, R Jin - Chemical Society Reviews, 2020 - pubs.rsc.org
Metal nanoclusters fill the gap between discrete atoms and plasmonic nanoparticles,
providing unique opportunities for investigating the quantum effects and precise structure …

Atomic-level doping of metal clusters

A Ghosh, OF Mohammed, OM Bakr - Accounts of Chemical …, 2018 - ACS Publications
Conspectus Atomically precise noble metal (mainly silver and gold) nanoclusters are an
emerging category of promising functional materials for future applications in energy …

Alloy clusters: Precise synthesis and mixing effects

S Hossain, Y Niihori, LV Nair, B Kumar… - Accounts of Chemical …, 2018 - ACS Publications
Conspectus Metal alloys exhibit functionalities unlike those of single metals. Such alloying
has drawn considerable research interest, particularly for nanoscale particles (metal …

Au 25 (SR) 18: the captain of the great nanocluster ship

X Kang, H Chong, M Zhu - Nanoscale, 2018 - pubs.rsc.org
Noble metal nanoclusters are in the intermediate state between discrete atoms and
plasmonic nanoparticles and are of significance due to their atomically accurate structures …

Catalytic Conversion of CO2 over Atomically Precise Gold-Based Cluster Catalysts

X Cai, G Li, W Hu, Y Zhu - ACS Catalysis, 2022 - ACS Publications
There are obstacles with using conventional nanoparticle catalysts for developing atomic-by-
atom tailoring of active sites in the heterogeneous catalysis field. However, atomically …

Customizing the structure, composition, and properties of alloy nanoclusters by metal exchange

S Wang, Q Li, X Kang, M Zhu - Accounts of chemical research, 2018 - ACS Publications
Conspectus The properties of metal materials can be greatly enriched by including various
elements to generate alloys. The galvanic replacement represents a classical method for the …

Thiolate‐protected metal nanoclusters: recent development in synthesis, understanding of reaction, and application in energy and environmental field

T Kawawaki, A Ebina, Y Hosokawa, S Ozaki, D Suzuki… - Small, 2021 - Wiley Online Library
Metal nanoclusters (NCs), which are composed of about 250 or fewer metal atoms, possess
great potential as novel functional materials. Fundamental research on metal NCs gradually …

Self‐Assembly of Precision Noble Metal Nanoclusters: Hierarchical Structural Complexity, Colloidal Superstructures, and Applications

JV Rival, P Mymoona, KM Lakshmi, Nonappa… - Small, 2021 - Wiley Online Library
Ligand protected noble metal nanoparticles are excellent building blocks for colloidal self‐
assembly. Metal nanoparticle self‐assembly offers routes for a wide range of multifunctional …

Atomically precise thiolate‐protected gold nanoclusters: Current status of designability of the structure and physicochemical properties

S Hossain, D Hirayama, A Ikeda, M Ishimi… - …, 2023 - Wiley Online Library
Thiolate (SR)‐protected gold nanoclusters (Aun (SR) m NCs) are a rare type of material
capable of simultaneously exhibiting multiple physicochemical properties well‐suited to …

Toward the creation of high-performance heterogeneous catalysts by controlled ligand desorption from atomically precise metal nanoclusters

T Kawawaki, Y Kataoka, M Hirata, Y Iwamatsu… - Nanoscale …, 2021 - pubs.rsc.org
Ligand-protected metal nanoclusters controlled by atomic accuracy (ie atomically precise
metal NCs) have recently attracted considerable attention as active sites in heterogeneous …