Organic peroxides in aerosol: key reactive intermediates for multiphase processes in the atmosphere
Organic peroxides (POs) are organic molecules with one or more peroxide (− O–O−)
functional groups. POs are commonly regarded as chemically labile termination products …
functional groups. POs are commonly regarded as chemically labile termination products …
Criegee intermediates and their impacts on the troposphere
Criegee intermediates (CIs), carbonyl oxides formed in ozonolysis of alkenes, play key roles
in the troposphere. The decomposition of CIs can be a significant source of OH to the …
in the troposphere. The decomposition of CIs can be a significant source of OH to the …
Criegee intermediates: production, detection and reactivity
In the context of tropospheric chemistry, Criegee intermediates denote carbonyl oxides with
biradical/zwitterionic character (R1R2COO) that form during the ozonolysis of alkenes. First …
biradical/zwitterionic character (R1R2COO) that form during the ozonolysis of alkenes. First …
Criegee intermediate reactions with carboxylic acids: A potential source of secondary organic aerosol in the atmosphere
R Chhantyal-Pun, B Rotavera… - ACS Earth and Space …, 2018 - ACS Publications
Trace atmospheric concentrations of carboxylic acids have a potent effect upon the
environment, where they modulate aqueous chemistry and perturb Earth's radiative balance …
environment, where they modulate aqueous chemistry and perturb Earth's radiative balance …
Ozonolysis can produce long-lived greenhouse gases from commercial refrigerants
Hydrofluoroolefins are being adopted as sustainable alternatives to long-lived fluorine-and
chlorine-containing gases and are finding current or potential mass-market applications as …
chlorine-containing gases and are finding current or potential mass-market applications as …
AtmoSpec–A Tool to Calculate Photoabsorption Cross-Sections for Atmospheric Volatile Organic Compounds
D Hollas, BFE Curchod - The Journal of Physical Chemistry A, 2024 - ACS Publications
Characterizing the photolysis processes undergone by transient volatile organic compounds
(VOCs) in the troposphere requires the knowledge of their photoabsorption cross-section …
(VOCs) in the troposphere requires the knowledge of their photoabsorption cross-section …
Calculating photoabsorption cross-sections for atmospheric volatile organic compounds
Characterizing the photochemical reactivity of transient volatile organic compounds (VOCs)
in our atmosphere begins with a proper understanding of their abilities to absorb sunlight …
in our atmosphere begins with a proper understanding of their abilities to absorb sunlight …
Radical formation by fine particulate matter associated with highly oxygenated molecules
Highly oxygenated molecules (HOMs) play an important role in the formation and evolution
of secondary organic aerosols (SOA). However, the abundance of HOMs in different …
of secondary organic aerosols (SOA). However, the abundance of HOMs in different …
Fates of organic hydroperoxides in atmospheric condensed phases
S Enami - The Journal of Physical Chemistry A, 2021 - ACS Publications
The fates of organic hydroperoxides (ROOHs) in atmospheric condensed phases are key to
understanding the oxidative and toxicological potentials of particulate matter. Recently …
understanding the oxidative and toxicological potentials of particulate matter. Recently …
Kinetics of the Reactions between the Criegee Intermediate CH2OO and Alcohols
SV Tadayon, ES Foreman, C Murray - The Journal of Physical …, 2017 - ACS Publications
Reactions of the simplest Criegee intermediate (CH2OO) with a series of alcohols have
been studied in a flash photolysis flow reactor. Laser photolysis of diiodomethane at 355 nm …
been studied in a flash photolysis flow reactor. Laser photolysis of diiodomethane at 355 nm …