Molecular main group metal hydrides
This review serves to document advances in the synthesis, versatile bonding, and reactivity
of molecular main group metal hydrides within Groups 1, 2, and 12–16. Particular attention …
of molecular main group metal hydrides within Groups 1, 2, and 12–16. Particular attention …
Chemistry of alkaline earth metals: It is not all ionic and definitely not boring!
KM Fromm - Coordination Chemistry Reviews, 2020 - Elsevier
Some scientists might consider group 2 chemistry as “boring, closed shell and all ionic,
aqueous chemistry, where everything is known! It is not worth investigating”. How wrong …
aqueous chemistry, where everything is known! It is not worth investigating”. How wrong …
A Planar Nickelaspiropentane Complex with Magnesium-Based Metalloligands: Synthesis, Structure, and Synergistic Dihydrogen Activation
Y Cai, S Jiang, T Rajeshkumar… - Journal of the American …, 2022 - ACS Publications
The nature of transition-metal–olefin bonding has been explained by the Dewar–Chatt–
Duncanson model within a continuum of two extremes, namely, a π-complex and a …
Duncanson model within a continuum of two extremes, namely, a π-complex and a …
Molecular magnesium hydrides
D Mukherjee, J Okuda - Angewandte Chemie International …, 2018 - Wiley Online Library
Solid magnesium hydride [MgH2]∞ has been pursued as a potential hydrogen‐storage
material. Organic chemists were rather interested in soluble magnesium hydride reagents …
material. Organic chemists were rather interested in soluble magnesium hydride reagents …
Ring‐Shaped Phosphinoamido‐Magnesium‐Hydride Complexes: Syntheses, Structures, Reactivity, and Catalysis
L Fohlmeister, A Stasch - Chemistry–A European Journal, 2016 - Wiley Online Library
A series of magnesium (II) complexes bearing the sterically demanding phosphinoamide
ligand, L−= Ph2PNDip−, Dip= 2, 6‐diisopropylphenyl, including heteroleptic magnesium …
ligand, L−= Ph2PNDip−, Dip= 2, 6‐diisopropylphenyl, including heteroleptic magnesium …
Low oxidation state and hydrido group 2 complexes: synthesis and applications in the activation of gaseous substrates
Numerous industrial processes utilise gaseous chemical feedstocks to produce useful
chemical products. Atmospheric and other small molecule gases, including anthropogenic …
chemical products. Atmospheric and other small molecule gases, including anthropogenic …
Stabilization of calcium hydride complexes by fine tuning of amidinate ligands
A Causero, G Ballmann, J Pahl, H Zijlstra… - …, 2016 - ACS Publications
A range of symmetric amidinate ligands RAmAr (R is backbone substituent, Ar is N
substituent) have been investigated for their ability to stabilize calcium hydride complexes of …
substituent) have been investigated for their ability to stabilize calcium hydride complexes of …
Reduction of cyclic and linear organic carbonates using a readily available magnesium catalyst
Efficient reduction of cyclic and linear organic carbonates catalyzed by a readily available
earth alkaline catalyst has been achieved. The described homogenous reaction based on a …
earth alkaline catalyst has been achieved. The described homogenous reaction based on a …
Alkaline earth metal compounds of methylpyridinato β-diketiminate ligands and their catalytic application in hydroboration of aldehydes and ketones
Ever increasing demand for green and sustainable chemical processes has set up a drive to
replace transition metals with earth-abundant, nontoxic, and environmentally benign …
replace transition metals with earth-abundant, nontoxic, and environmentally benign …
Molecular Calcium Hydride: Dicalcium Trihydride Cation Stabilized by a Neutral NNNN‐Type Macrocyclic Ligand
V Leich, TP Spaniol, L Maron… - Angewandte Chemie …, 2016 - Wiley Online Library
Hydrogenolysis of bis (triphenylsilyl) calcium containing the neutral NNNN‐type macrocyclic
amine ligand Me4TACD [Ca (Me4TACD)(SiPh3) 2](2), gave the cationic dinuclear calcium …
amine ligand Me4TACD [Ca (Me4TACD)(SiPh3) 2](2), gave the cationic dinuclear calcium …