Conspectus To improve the efficacy of molecular syntheses, researchers wish to capitalize
upon the selective modification of otherwise inert C–H bonds. The past two decades have …

The past few decades have witnessed a complete renaissance in the field of Ni (IV)
catalysis. The properties of Ni (IV) complexes, such as, it undergoes rapid reductive …

Nickel‐catalyzed electrochemical C− H aminations were accomplished by chemo‐and
position‐selective C− H activation with ample scope. Detailed mechanistic studies …

We describe a series of air‐stable NiIII complexes supported by a simple, robust
naphthyridine‐based ligand. Access to the high‐valent oxidation state is enabled by the CF3 …

This paper describes the one-electron interconversions of isolable NiIII and NiIV complexes
through their reactions with carbon-centered radicals (R•). First, model NiIII complexes are …

The synthesis, characterization, and C (sp2)− CF3 reductive elimination of stable aryl [tris
(trifluoromethyl)] cuprate (III) complexes [nBu4N][Cu (Ar)(CF3) 3] are described. Mechanistic …

Ni catalysis constitutes an active research arena with notable applications in diverse fields.
By analogy with its parent element palladium, Ni catalysts provide an appealing entry to …

The increasing pharmaceutical importance of trifluoromethylarenes has stimulated the
development of more efficient trifluoromethylation reactions. Tremendous efforts have …

The preparation of the difluoromethylated organogold (III) complex cis-[Au (PCy3)(4-F-
C6H4)(CF2H)(Cl)](3) and its Ar–CF2H reductive elimination are described. In the presence …

Based on previous work related to the design and application of rigid tridentate phosphine–
pyridine–phenyl coordination offered by a PNC‐pincer ligand upon cyclometalation to …