Coordinatively unsaturated metal sites (open metal sites) in metal–organic frameworks: design and applications

Ü Kökçam-Demir, A Goldman, L Esrafili… - Chemical Society …, 2020 - pubs.rsc.org
Metal–organic frameworks (MOFs) can contain open metal sites (OMS) or coordinatively
unsaturated sites (CUS) or open coordination sites (OCS) when vacant Lewis acid sites on …

Mixed‐metal MOF‐74 templated catalysts for efficient carbon dioxide capture and methanation

T Zurrer, K Wong, J Horlyck, EC Lovell… - Advanced Functional …, 2021 - Wiley Online Library
The vast chemical and structural tunability of metal–organic frameworks (MOFs) are
beginning to be harnessed as functional supports for catalytic nanoparticles spanning a …

Synthesis of nitrogen-rich nanoporous carbon materials with C3N-type from ZIF-8 for methanol adsorption

X Ma, L Li, Z Zeng, R Chen, C Wang, K Zhou… - Chemical Engineering …, 2019 - Elsevier
Abstract The N-rich nitrogen (25.7%) porous carbon with high surface area was prepared by
using N-rich ZIF-8 as a template and precursor and urea as a secondary nitrogen source …

In Situ Single-crystal X-ray Diffraction Studies of Physisorption and Chemisorption of SO2 within a Metal–Organic Framework and Its Competitive Adsorption with …

RM Main, SM Vornholt, R Ettlinger… - Journal of the …, 2024 - ACS Publications
Living on an increasingly polluted planet, the removal of toxic pollutants such as sulfur
dioxide (SO2) from the troposphere and power station flue gas is becoming more and more …

Impedance-Based Detection of NO2 Using Ni-MOF-74: Influence of Competitive Gas Adsorption

LJ Small, SM Vornholt, SJ Percival… - … Applied Materials & …, 2023 - ACS Publications
Chemically robust, low-power sensors are needed for the direct electrical detection of toxic
gases. Metal–organic frameworks (MOFs) offer exceptional chemical and structural tunability …

Polypyrrole decorated metal–organic frameworks for supercapacitor devices

N Patterson, B Xiao, A Ignaszak - RSC advances, 2020 - pubs.rsc.org
Due to their large specific surface areas and porosity, metal–organic frameworks (MOFs)
have found many applications in catalysis, gas separation, and gas storage. However, their …

Augmented Reality for Enhanced Visualization of MOF Adsorbents

LT Glasby, R Oktavian, K Zhu, JL Cordiner… - Journal of Chemical …, 2023 - ACS Publications
Augmented reality (AR) is an emerging technique used to improve visualization and
comprehension of complex 3D materials. This approach has been applied not only in the …

An experimental and computational study of CO 2 adsorption in the sodalite-type M-BTT (M= Cr, Mn, Fe, Cu) metal–organic frameworks featuring open metal sites

M Asgari, S Jawahery, ED Bloch, MR Hudson… - Chemical …, 2018 - pubs.rsc.org
We present a comprehensive investigation of the CO2 adsorption properties of an
isostructural series of metal–organic frameworks, M-BTT (M= Cr, Mn, Fe, Cu; BTT3−= 1, 3, 5 …

Tuning expanded pores in metal–organic frameworks for selective capture and catalytic conversion of carbon dioxide

W Meng, Y Zeng, Z Liang, W Guo, C Zhi, Y Wu… - …, 2018 - Wiley Online Library
Three Co‐based isostructural MOF‐74‐III materials with expanded pores are synthesized,
with varied extent of fused benzene rings onto sidechain of same‐length ligands to finely …

Unexpected Diffusion Anisotropy of Carbon Dioxide in the Metal–Organic Framework Zn2(dobpdc)

AC Forse, MI Gonzalez, RL Siegelman… - Journal of the …, 2018 - ACS Publications
Metal–organic frameworks are promising materials for energy-efficient gas separations, but
little is known about the diffusion of adsorbates in materials featuring one-dimensional …