Transition metal-catalyzed cross-coupling reactions of alkyl metals and aryl halides or
pseudohalides have emerged as a powerful methodology for the formation of Csp3-Csp2 …

This critical review discusses specific chemical and physicochemical requirements which
must be met for organic compounds to be considered as promising materials for applications …

Though often perceived as the simple metaphorical hybrid of synthetic inorganic and
organic chemistry, synthetic organometallic chemistry continues to vigorously differentiate …

Although the first chiral organosulfur compounds were obtained at the beginning of this
century, they have received more attention since the early 1960s. Initially, chiral sulfur …

Stereoselective functionalizations of organic molecules are of great importance to modern
synthesis. A stereoselective preparation of pharmaceutically active molecules is often …

A simple yet powerful Ni catalyst can be used to promote direct arylations of α-halocarbonyl
compounds, including a range of esters, amides, and ketones, with various arylboronic acids …

Phosphine ligands have been demonstrated to have an effect on reactivity and selectivity in
the competitive intramolecular palladium‐catalysed Suzuki–Miyaura coupling of dibromo …

Cyclometalation of 3-(2-naphthyl)-d-alanine methyl ester is achieved by reacting the
corresponding hydrochloride salt and Pd (OAc) 2 in a 1: 1 molar ratio (acetonitrile, room …

A nickel-catalyzed cross-electrophile coupling of aryl iodides with α-bromo sulfoxide to
access a diverse array of aryl benzyl sulfoxides has been discovered. These reactions …

Abstract Palladium‐catalyzed C C bond formation involving secondary sp3‐hybridized
carbon is described. These reactions occur with secondary 1‐bromoethyl arylsulfoxides and …