Ion spectroscopy in methane activation

J Roithová, JM Bakker - Mass Spectrometry Reviews, 2022 - Wiley Online Library
This review is devoted to ion spectroscopy studies of complexes relevant for the
understanding of methane activation with metal ions and clusters. Methane activation starts …

Quantitative Aspects of Gas-Phase Metal Ion Chemistry: Conservation of Spin, Participation of f Orbitals, and C–H Activation and C–C Coupling

PB Armentrout - The Journal of Physical Chemistry A, 2023 - ACS Publications
In this Featured Article, I reflect on over 40 years of guided ion beam tandem mass
spectrometry (GIBMS) studies involving atomic metal cations and their clusters throughout …

IR spectroscopic characterization of [M, C, 2H]+(M= Ru and Rh) products formed by reacting 4d transition metal cations with oxirane: Spectroscopic evidence for …

FJ Wensink, CE Smink, BC Stevenson… - Physical Chemistry …, 2024 - pubs.rsc.org
A combination of infrared multiple-photon dissociation (IRMPD) action spectroscopy and
quantum chemical calculations was employed to investigate the [M, C, 2H]+(M= Ru and Rh) …

IR Spectroscopic Characterization of Methane Adsorption on Copper Clusters Cun+ (n = 2–4)

OV Lushchikova, S Reijmer… - Journal of the …, 2022 - ACS Publications
The interaction of CH4 with cationic copper clusters has been studied with infrared-multiple
photon dissociation (IRMPD) spectroscopy. Cu n+(n= 2–4) formed by laser ablation were …

IR spectroscopic characterization of 3d transition metal carbene cations, FeCH 2+ and CoCH 2+: periodic trends and a challenge for DFT approaches

FJ Wensink, CE Smink, PB Armentrout… - Physical Chemistry …, 2024 - pubs.rsc.org
A combination of IR multiple-photon dissociation (IRMPD) action spectroscopy and quantum
chemical calculations was employed to investigate the [M, C, 2H]+(M= Fe and Co) species …

Carbide Dihydrides: Carbonaceous Species Identified in Ta4+‐Mediated Methane Dehydrogenation

J Lengyel, N Levin, FJ Wensink… - Angewandte Chemie …, 2020 - Wiley Online Library
The products of methane dehydrogenation by gas‐phase Ta4+ clusters are structurally
characterized using infrared multiple photon dissociation (IRMPD) spectroscopy in …

[HTML][HTML] Structural characterization of [M, C, 2H]+ products formed by reaction of 5d metal cations Pt+ and Ir+ with ethylene oxide and Ta+ with methane using …

JM Bakker, CJ Owen, SW Nooteboom… - Journal of Molecular …, 2021 - Elsevier
Structural characterization of gas-phase [M, C, 2H]+(M= Ta, Ir, Pt), formed by reacting laser
ablation formed M+ with ethylene oxide (cC 2 H 4 O) or methane under multiple collision …

Vibrational Spectroscopy of Intermediates and C–H Activation Products of Sequential Zr+ Reactions with CH4

J Kozubal, T Heck, RB Metz - The Journal of Physical Chemistry A, 2020 - ACS Publications
Vibrational spectra of the entrance channel complexes Zr+ (CH4) n (Ar)(n= 1–2) and Zr+
(CH4) n (n= 3–4) and the reaction products ZrC3H10+, ZrC4H13+, ZrC4H14+, and …

[HTML][HTML] IR spectroscopic characterization of products of methane and cyclopropane activation by Ru cations

FJ Wensink, D Pradeep, PB Armentrout… - International Journal of …, 2024 - Elsevier
Methane and cyclopropane (cC 3 H 6) were reacted with Ru+ ions in a room temperature
ion trap and the resulting products were identified using a combination of mass …

Cation‐π Interactions between a Noble Metal and a Polyfunctional Aromatic Ligand: Ag+(benzylamine)

D Corinti, A Maccelli, B Chiavarino… - … A European Journal, 2022 - Wiley Online Library
The structure of an isolated Ag+ (benzylamine) complex is investigated by infrared multiple
photon dissociation (IRMPD) spectroscopy complemented with quantum chemical …