MIDA‐and TIDA‐Boronates Stabilize α‐Radicals Through B− N Hyperconjugation

AJ LaPorte, JE Feldner, JC Spies… - Angewandte Chemie …, 2023 - Wiley Online Library
Multifunctional organoboron compounds increasingly enable the simple generation of
complex, Csp3‐rich small molecules. The ability of boron‐containing functional groups to …

Substituent Effects in Bioorthogonal Diels–Alder Reactions of 1, 2, 4, 5‐Tetrazines

N Houszka, H Mikula… - Chemistry–A European …, 2023 - Wiley Online Library
Abstract 1, 2, 4, 5‐Tetrazines are increasingly used as reactants in bioorthogonal chemistry
due to their high reactivity in Diels–Alder reactions with various dienophiles. Substituents in …

Mechanistic Insights into the Stepwise (4+ 2) Cycloaddition toward Chiral Fused Uracil Derivatives

E Marcantonio, F Zanardi, C Curti… - Advanced Synthesis & …, 2023 - Wiley Online Library
The mechanism of the previously reported stereoselective (4+ 2) cycloaddition of N‐
protected 6‐methyluracil‐5‐carbaldehydes and (E)‐β‐nitrostyrenes catalyzed by …

A computational study of the reaction mechanism involved in the fast cleavage of an unconstrained amide bond assisted by an amine intramolecular nucleophilic …

SA Cuesta, L Rincón, FJ Torres… - Journal of …, 2021 - Wiley Online Library
In the present work, the fast amide bond cleavage of [3‐((1R, 5S, 7s)‐3‐azabicyclo [3.3. 1]
nonane‐7‐carbonyl)‐3‐azabicyclo [3.3. 1] nonane‐7‐carboxylic acid (bi‐ATDO)], through …

C− H Bond Activation in Ru‐Catalyzed Reactions of Arenes with Olefins: Theoretical Insights into Hydroarylation and Oxidative Coupling Mechanisms

I Efremenko, JML Martin - Israel Journal of Chemistry, 2023 - Wiley Online Library
A detailed mechanistic density functional theory (DFT) and coupled cluster study of Csp²− H
activation in benzene and methyl acrylate by the catalyst RuClm (CO) n (m= 2, 3; n= 0–4) is …

Copper-catalyzed Intermolecular Regio-and Enantioselective Hy-drosilylation of Alkenes with Prochiral Silanes

YH Xu, XY Zhu, W Gao, JL Xu, ZL Wang, J Zhao - 2024 - researchsquare.com
This study presents a copper-catalyzed, substrate-controlled regio-and enantioselective
intermolecular hydrosilylation method capable of accommodating a broad scope of alkenes …