The present review offers an overview of the current approaches for the photochemical and
photocatalytic generation of reactive intermediates and their application in the formation of …

In recent years, radical C–C bond cleavage reactions have been increasingly understood
and used to perform transformations that complement traditional ionic processes. However …

Recently, Baird (anti) aromaticity has been referred to as a description of excited-state (anti)
aromaticity. With the term of Baird's rule, recent studies have intensively verified that the …

Gain of aromaticity or relief of antiaromaticity along a reaction path are important factors to
consider in mechanism studies. Analysis of such changes along potential energy surfaces …

Baird’s rules at the tipping point | Nature Chemistry Skip to main content Thank you for visiting
nature.com. You are using a browser version with limited support for CSS. To obtain the best …

The Baldwin rules constitute one of the clearest examples of the success which can be
obtained through the application of stereoelectronic concepts to reaction design. With …

Photo‐mediated 6π cyclization is a valuable method for the formation of fused heterocyclic
systems. Here we demonstrate that irradiation of cyclic 2‐aryloxyketones with blue LED light …

For the concept of aromaticity, energetic quantification is crucial. However, this has been
elusive for excited-state (Baird) aromaticity. Here we report our serendipitous discovery of …

A highly regio-and stereoselective synthesis of functionalized benzofulvenes via Rh (III)-
catalyzed cascade reactions of benzoyl acetonitrile/methylsulfone/acetate with propargyl …

1, 3-Dien-5-ynes have been extensively used as starting materials for the synthesis of a
wide number of different carbo-and heterocycles. The aim of this review is to give an …