Shedding light on bifunctional luminescent spin crossover materials

MK Javed, A Sulaiman, M Yamashita, ZY Li - Coordination Chemistry …, 2022 - Elsevier
The spin crossover (SCO) phenomenon has witnessed remarkable progress in applications
since it was first discovered almost a century ago. Specifically, materials that exhibit SCO …

Synergistic strategies for the synthesis of Fe (II)-based bifunctional fluorescent spin-crossover materials

K Sun, JP Xue, ZS Yao, J Tao - Dalton Transactions, 2022 - pubs.rsc.org
Spin-crossover (SCO) materials have been extensively investigated in the past few decades
with promising applications in a wide range of fields including displays, sensors, and …

Stimuli-responsive magnetic materials: impact of spin and electronic modulation

K Kaushik, S Mehta, M Das, S Ghosh… - Chemical …, 2023 - pubs.rsc.org
Addressing molecular bistability as a function of external stimuli, especially in spin-crossover
(SCO) and metal-to-metal electron transfer (MMET) systems, has seen a surge of interest in …

Synergetic Spin-Crossover and Luminescent Properties in a Multifunctional 2D Iron (II) Coordination Polymer

J Wang, M Kong, XJ Song, Y Jing, Y Zhao… - Inorganic …, 2022 - ACS Publications
We designed and synthesized a strong fluorescent tetradentate pyridine ligand, 3, 6, 11, 12-
tetra (pyridin-4-yl) dibenzo [a, c] phenazine (TPDP), by covalently grafting pyridyl to …

Coexistence of luminescence and spin-crossover in 2D iron (II) Hofmann clathrates modulated through guest encapsulation

R Turo-Cortés, M Meneses-Sánchez… - Journal of Materials …, 2022 - pubs.rsc.org
The search for advanced multifunctional materials displaying two or more simultaneous and
correlated physicochemical properties represents a key step in developing further practical …

Manipulating Fluorescence by Photo-switched Spin-state Conversions in an Iron (II)-based SCO-MOF

FF Yan, WJ Jiang, NT Yao, PD Mao, L Zhao… - Chemical …, 2023 - pubs.rsc.org
Manipulating fluorescence by photo-switched spin-state conversions is an attractive
prospect for applications in smart magneto-optical materials and devices. The challenge is …

Fluorescence emission modulation in cyanido-bridged Fe (II) spin crossover coordination polymers

XR Wu, ZK Liu, M Zeng, MX Chen, J Tao, SQ Wu… - Science China …, 2022 - Springer
Synergistic fluorescent spin crossover (SCO) bifunctional molecular materials have novel
applications in the molecule-based magneto-optical switches. Herein, we report two novel …

Two-Step Spin Crossover in Hofmann-Type Coordination Polymers [Fe(2-phenylpyrazine)2{M(CN)2}2] (M = Ag, Au)

VM Hiiuk, SI Shylin, DD Barakhtii, DM Korytko… - Inorganic …, 2022 - ACS Publications
Two 2D Hofmann-type complexes of the composition [Fe (Phpz) 2 {M (CN) 2} 2](where
Phpz= 2-phenylpyrazine; M= Ag, Au) have been synthesized, and their spin-crossover …

A Smart Molecule Showing Spin Crossover Responsive Aggregation-Induced Emission

C Yi, YS Meng, L Zhao, NT Yao, Q Liu, W Wen… - CCS …, 2023 - chinesechemsoc.org
The utilization of spin crossover (SCO) to modulate the luminescence properties in smart
multifunctional materials and multichannel sensors is promising. However, it is challenging …

Spin-state switching: chemical modulation and the impact of intermolecular interactions in manganese (iii) complexes

S Bagchi, S Kamilya, S Mehta, S Mandal… - Dalton …, 2023 - pubs.rsc.org
A series of mononuclear manganese (III) complexes [Mn (X-sal2-323)](ReO4)(X= 5 Cl, 1; X=
5 Br, 2; X= 3, 5 Cl, 3; X= 3, 5 Br, 4; and X= 5 NO2, 5), containing hexadentate ligands …