Isoreticular chemistry within metal–organic frameworks for gas storage and separation

W Fan, X Zhang, Z Kang, X Liu, D Sun - Coordination chemistry reviews, 2021 - Elsevier
Precise control of the pore size and environment of metal–organic framework (MOF) is a
necessary condition for achieving high performance of gas adsorption and separation. After …

Energy-efficient separation alternatives: metal–organic frameworks and membranes for hydrocarbon separation

L Yang, S Qian, X Wang, X Cui, B Chen… - Chemical Society …, 2020 - pubs.rsc.org
Hydrocarbon separation is one of the most critically important and complex industrial
separation processes, offering versatile bulk chemicals and vital support to the national …

Orthogonal-array dynamic molecular sieving of propylene/propane mixtures

H Zeng, M Xie, T Wang, RJ Wei, XJ Xie, Y Zhao, W Lu… - Nature, 2021 - nature.com
Rigid molecular sieving materials work well for small molecules with the complete exclusion
of large ones,–, and molecules with matching physiochemical properties may be separated …

Programmed fluorine binding engineering in anion-pillared metal-organic framework for record trace acetylene capture from ethylene

XW Gu, E Wu, JX Wang, HM Wen, B Chen, B Li… - Science …, 2023 - science.org
Porous physisorbents are attractive candidates for selective capture of trace gas or volatile
compounds due to their low energy footprints. However, many physisorbents suffer from …

Porous metal-organic frameworks for gas storage and separation: Status and challenges

H Li, L Li, RB Lin, W Zhou, Z Zhang, S Xiang, B Chen - EnergyChem, 2019 - Elsevier
Gases are widely used as energy resources for industry and our daily life. Developing
energy cost efficient porous materials for gas storage and separation is of fundamentally and …

Ultramicroporous hydrogen-bonded organic framework material with a thermoregulatory gating effect for record propylene separation

Y Chen, Y Yang, Y Wang, Q Xiong, J Yang… - Journal of the …, 2022 - ACS Publications
Propane/propylene separation is one of the most challenging and energy-consuming but
most important tasks in the petrochemical industry. Herein, a stable hydrogen-bonded …

Engineering Supramolecular Binding Sites in a Chemically Stable Metal‐Organic Framework for Simultaneous High C2H2 Storage and Separation

K Shao, HM Wen, CC Liang, X Xiao… - Angewandte Chemie …, 2022 - Wiley Online Library
Developing porous materials to overcome the trade‐off between adsorption capacity and
selectivity for C2H2/CO2 separation remains a challenge. Herein, we report a stable HKUST …

Designer metal–organic frameworks for size‐exclusion‐based hydrocarbon separations: progress and challenges

H Wang, Y Liu, J Li - Advanced Materials, 2020 - Wiley Online Library
The separation of hydrocarbons is of primary importance in the petrochemical industry but
remains a challenging process. Hydrocarbon separations have traditionally relied …

Separation and purification of hydrocarbons with porous materials

Y Wu, BM Weckhuysen - Angewandte Chemie International …, 2021 - Wiley Online Library
This Minireview focuses on the developments of the adsorptive separation of
methane/nitrogen, ethene/ethane, propene/propane mixtures as well as on the separation of …

Pore space partition of metal-organic frameworks for gas storage and separation

AN Hong, H Yang, X Bu, P Feng - EnergyChem, 2022 - Elsevier
Pore space partition (PSP) concept is a synthetic design concept and can also serve as a
structure analysis method useful for next-step synthetic planning and execution. PSP …