Mechanochemistry: new tools to navigate the uncharted territory of “impossible” reactions

F Cuccu, L De Luca, F Delogu, E Colacino… - …, 2022 - Wiley Online Library
Mechanochemical transformations have made chemists enter unknown territories, forcing a
different chemistry perspective. While questioning or revisiting familiar concepts belonging …

Time‐resolved in situ monitoring of mechanochemical reactions

AAL Michalchuk, F Emmerling - … Chemie International Edition, 2022 - Wiley Online Library
Mechanochemical transformations offer environmentally benign synthesis routes, whilst
enhancing both the speed and selectivity of reactions. In this regard, mechanochemistry …

Mechanochemistry of gaseous reactants

C Bolm, JG Hernández - Angewandte Chemie International …, 2019 - Wiley Online Library
In recent years, the application of mechanical energy to chemical systems has repeatedly
proven beneficial to facilitate chemical transformations in various areas in chemistry. Today …

Synthesis without solvent: consequences for mechanochemical reactivity

LE Wenger, TP Hanusa - Chemical Communications, 2023 - pubs.rsc.org
Solvents are so nearly omnipresent in synthetic chemistry that a classic question for their
use has been:“What is the best solvent for this reaction?” The increasing use of …

Stainless steel-initiated chloro sulfoximidations of allenes under solvent-free conditions in a ball mill

D Kong, MM Amer, C Bolm - Green Chemistry, 2022 - pubs.rsc.org
We report mechanochemical regioselective chloro sulfoximidations of allenes through
stainless steel-initiated radical addition reactions at ambient temperature under solvent-free …

Mechanochemical catalytic transfer hydrogenation of aromatic nitro derivatives

T Portada, D Margetić, V Štrukil - Molecules, 2018 - mdpi.com
Mechanochemical ball milling catalytic transfer hydrogenation (CTH) of aromatic nitro
compounds using readily available and cheap ammonium formate as the hydrogen source …

Bronze age of direct mechanocatalysis: How alloyed milling materials advance coupling in ball mills

CG Vogt, M Oltermann, W Pickhardt… - Advanced Energy …, 2021 - Wiley Online Library
The copper‐catalyzed Glaser coupling is conducted mechanochemically, with the milling
balls and vessels being the catalyst. Thus, neither catalyst powders nor soluble catalyst salts …

Stainless steel-mediated hydrogen generation from alkanes and diethyl ether and its application for arene reduction

Y Sawama, N Yasukawa, K Ban, R Goto… - Organic …, 2018 - ACS Publications
Hydrogen gas can be generated from simple alkanes (eg, n-pentane, n-hexane, etc.) and
diethyl ether (Et2O) by mechanochemical energy using a planetary ball mill (SUS304 …

In situ preparation of nanocrystalline Ni@ C and its effect on hydrogen storage properties of MgH2

L Li, Z Zhang, L Jiao, H Yuan, Y Wang - International Journal of Hydrogen …, 2016 - Elsevier
Nanocrystalline Ni@ C was fabricated by a self-template strategy using benzimidazole as
the reductant and carbon precursor, and it exhibited remarkable catalytic effect on hydrogen …

Mechanochemie gasförmiger Reaktanten

C Bolm, JG Hernández - Angewandte Chemie, 2019 - Wiley Online Library
In den letzten Jahren hat sich die Anwendung von mechanischer Energie auf chemische
Systeme wiederholt als vorteilhaft erwiesen, um chemische Umwandlungen in …