Copper (I) complexes for thermally activated delayed fluorescence: from photophysical to device properties

MJ Leitl, DM Zink, A Schinabeck, T Baumann… - Photoluminescent …, 2017 - Springer
Molecules that exhibit thermally activated delayed fluorescence (TADF) represent a very
promising emitter class for application in electroluminescent devices since all electrically …

Enlightening developments in 1, 3-P, N-ligand-stabilized multinuclear complexes: A shift from catalysis to photoluminescence

MK Rong, F Holtrop, JC Slootweg… - Coordination Chemistry …, 2019 - Elsevier
P, N-ligands provide the ideal spatial separation to facilitate homo and hetero metal-metal
interactions to access multinuclear complexes. The rich chemistry of such complexes …

Ligand control of structural diversity in luminescent hybrid copper (I) iodides

S Wang, EE Morgan, S Panuganti, L Mao… - Chemistry of …, 2022 - ACS Publications
Copper (I) iodide hybrids are of interest for next-generation lighting technologies because of
their efficient luminescence in the absence of rare-earth elements. Here, we report 10 …

Noncovalent Chelation by Halogen Bonding in the Design of Metal-Containing Arrays: Assembly of Double σ-Hole Donating Halolium with CuI-Containing O,O …

AV Semenov, SV Baykov, NS Soldatova… - Inorganic …, 2023 - ACS Publications
Five new copper (I) complexes─ composed of the paired dibenzohalolium and [CuL2]−(L=
1, 2, 4-oxadiazolate) counterions in which O, O-atoms of the anion are simultaneously linked …

New Cu (I) halide complexes showing TADF combined with room temperature phosphorescence: The balance tuned by halogens

AY Baranov, AS Berezin, DG Samsonenko… - Dalton …, 2020 - pubs.rsc.org
A series of Cu (I) halide complexes derived from tris (2-pyridyl) phosphine (Py3P),[Cu2
(Py3P) 2X2](X= Cl, Br, I), have been synthesized by a straightforward reaction in solution or …

Keep it tight: a crucial role of bridging phosphine ligands in the design and optical properties of multinuclear coinage metal complexes

AV Paderina, IO Koshevoy, EV Grachova - Dalton Transactions, 2021 - pubs.rsc.org
Copper subgroup metal ions in the+ 1 oxidation state are classical candidates for
aggregation via non-covalent metal–metal interactions, which are supported by a number of …

Oligophosphine-thiocyanate copper (I) and silver (I) complexes and their borane derivatives showing delayed fluorescence

G Chakkaradhari, T Eskelinen, C Degbe… - Inorganic …, 2019 - ACS Publications
The series of chelating phosphine ligands, which contain bidentate P 2 (bis [(2-
diphenylphosphino) phenyl] ether, DPEphos; 4, 5-bis (diphenylphosphino)-9, 9 …

The assembly of unique hexanuclear copper (I) complexes with effective white luminescence

ID Strelnik, IR Dayanova, IE Kolesnikov… - Inorganic …, 2019 - ACS Publications
The unique L2Cu6I6 complexes containing two Cu3I3 units have been obtained via reaction
of 1, 5-diaza-3, 7-diphosphacyclooctanes bearing ethylpyridyl substituents at phosphorus …

Copper(I) Complexes Bearing 1,2-Phenyl-Bridged PN, PNP, and NPN Chelate Ligands: Structures and Phosphorescence

C Zeng, N Wang, T Peng, S Wang - Inorganic Chemistry, 2017 - ACS Publications
With the aim to obtain new phosphorescent Cu (I) compounds, several new 1, 2-phenyl-
bridged P∧ N, P∧ N∧ P, and N∧ P∧ N chelate ligands were designed and synthesized …

Emission and Luminescent Vapochromism Control of Octahedral Cu4I4 Complexes by Conformationally Restricted P,N Ligands

I Strelnik, A Shamsieva… - … A European Journal, 2023 - Wiley Online Library
Abstract A conformationally restricted P, N‐ligand capable of the design of polynuclear
copper (I) complexes was synthesized via the reaction of primary pyridylphosphine …