Dynamic Covalent Chemistry as a Facile Route to Unusual Main‐Group Thiolate Assemblies and Disulfide Hoops and Cages

NM Phan, EG Percástegui, DW Johnson - ChemPlusChem, 2020 - Wiley Online Library
Abstract Dynamic Covalent Chemistry (DCC)–combining the robustness of covalent bonds
with the self‐correcting nature of supramolecular chemistry–facilitates the modular synthesis …

A structural survey of poly-functional dithiocarbamate ligands and the aggregation patterns they sustain

SM Lee, ERT Tiekink - Inorganics, 2021 - mdpi.com
An overview is presented of the crystal structures of transition metal, main group element,
and lanthanide compounds containing poly-functional dithiocarbamate ligands, namely …

Mercurophilic interactions

H Schmidbaur, A Schier - Organometallics, 2015 - ACS Publications
The widely confirmed abundance of aurophilic interactions in the structural chemistry of gold
(I) compounds gives reason to scrutinize the evidence for analogous mercurophilic …

A Computational Chemistry Investigation of the Influence of Steric Bulk of Dithiocarbamato-Bound Organic Substituents upon Spodium Bonding in Three Homoleptic …

RM Gomila, ERT Tiekink, A Frontera - Inorganics, 2023 - mdpi.com
Three homoleptic Hg (S2CNR2) 2, for R= ethyl (1), isobutyl (2), and cyclohexyl (3),
compounds apparently exhibit a steric-dependent supramolecular association in their …

Halogen··· halogen interactions in the assembly of high-dimensional supramolecular coordination polymers based on 3, 5-diiodobenzoic acid

B Li, MM Dong, HT Fan, CQ Feng, SQ Zang… - Crystal growth & …, 2014 - ACS Publications
The synthesis and determination of the crystal structures of eight mixed-ligand divalent
coordination polymers based on 3, 5-diiodobenzoic acid (HL) and ancillary nitrogen ligands …

Bis[bis(N-2-hydroxyethyl,N-isopropyl-dithiocarbamato)mercury(II)]2: crystal structure and Hirshfeld surface analysis

MM Jotani, YS Tan, ERT Tiekink - Zeitschrift für Kristallographie …, 2016 - degruyter.com
The presence of both κ2-chelating and μ2, κ2-tridentate bridging dithiocarbamate ligands in
centrosymmetric {Hg [S2CN (iPr) CH2CH2OH] 2} 2 (1) leads to globular aggregates that are …

An unusual mercury (II) diisopropyldithiocarbamate coordination polymer

A Angeloski, A Rawal, M Bhadbhade… - Crystal Growth & …, 2019 - ACS Publications
A new polymeric mercury (II) diisopropyldithiocarbamate complex was synthesized by the
reaction of sodium diisopropyldithiocarbamate with excess HgCl2 in water. The precise …

Mercury (I) nitroprusside: A 2D structure supported on homometallic interactions

H Osiry, A Cano, L Reguera, AA Lemus-Santana… - Journal of Solid State …, 2015 - Elsevier
The pentacyanonitrosylferrate complex anion,[Fe (CN) 5 NO] 2−, forms an insoluble solid
with Hg (I) ion, of formula unit Hg 2 [Fe (CN) 5 NO]· 2H 2 O, whose crystal structure and …

Monomeric and tetrameric mercury (II) complexes with iodo and N2O2/N3O ligands: Structure and blue luminescence

M Cho, HJ Shin, DKA Kusumahastuti, H Yeo… - Inorganica Chimica …, 2020 - Elsevier
The reaction of mercury (II) iodide and potential tetradentate ligand N-(2-pyridylmethyl)
iminodiethanol (H 2 pmide) or N, N-bis (2-pyridylmethyl)-2-aminoethanol (bpaeOH) leads to …

Alkyl linker effects on the coordination topology of ditopic di (2-pyridylmethyl) amine carboxylate ligands with Zn II and Cu II: polymers vs. macrocycles

K Rodpun, AG Blackman, MG Gardiner, EW Tan… - …, 2015 - pubs.rsc.org
A series of ditopic ω-di (2-pyridylmethyl) amine carboxylic acid ligands incorporating a range
of n-alkyl linkers (CnCOOH, n= 3–5, 7, 10 and 11) have been synthesised. Solution phase …