Tuning dynamic mechanical response in metallopolymer networks through simultaneous control of structural and temporal properties of the networks

D Mozhdehi, JA Neal, SC Grindy, Y Cordeau… - …, 2016 - ACS Publications
Tunable mechanical response under dynamic and static loading is desirable for many
technological applications. Traditionally, mechanical performance of polymeric materials is …

Masking Strategy Constructed Metal Coordination Hydrogels with Improved Mechanical Properties for Flexible Electronic Sensors

X Guan, S Zheng, B Zhang, X Sun… - … Applied Materials & …, 2024 - ACS Publications
Metal coordination hydrogels (MC-HGs) that introduce dynamically coordinate bonds
together with metal ionic conduction have attracted considerable attention in flexible …

Luminescent complexes made from chelating isocyanide ligands and earth-abundant metals

LA Büldt, OS Wenger - Dalton Transactions, 2017 - pubs.rsc.org
In this invited frontier article, recently discovered d6 and d10 complexes with long-lived
metal-to-ligand charge transfer (MLCT) excited states are highlighted. Chelating …

Coordination Geometry and Mineralization in Self-Healing Mussel-Inspired Hydrogels

M Ahmadi, G Pareras, MB Yeamin… - Chemistry of …, 2024 - ACS Publications
Mussel-inspired polymeric materials have found a broad range of applications not only in
adhesives, coatings, and tough hydrogels but thanks to self-healing and stimuli …

Photoswitchable transition metal complexes with azobenzene-functionalized imine-based ligands: structural and kinetic analysis

G Markiewicz, A Walczak, F Perlitius, M Piasecka… - Dalton …, 2018 - pubs.rsc.org
We report on the characterization of two imine type ligands containing photoresponsive
azobenzene units as side groups and their transition metal ions complexes. The ligands …

Programmable mechanical properties from a worm jaw-derived biopolymer through hierarchical ion exposure

MK Gupta, KA Becknell, MG Crosby… - … applied materials & …, 2018 - ACS Publications
Mechanisms of biomaterial sclerotization in natural systems promise new insights into how
the mechanical properties of engineered materials may be dynamically modulated. One …

Metal-coordination crosslinked N-polyindoles as recyclable high-performance thermosets and nondestructive detection for their tensile strength and glass transition …

G Chang, C Wang, M Du, S Liu, L Yang - Chemical Communications, 2018 - pubs.rsc.org
Metal coordination crosslinking between stiff N-polyindole chains was constructed, and the
crosslinked films exhibited high tensile strength, high heat resistance and excellent polar …

Recyclable Cu (II)‐coordination crosslinked poly (benzimidazolyl pyridine) s as high‐performance polymers

C Wang, L Yang, G Chang - Macromolecular Rapid …, 2018 - Wiley Online Library
Crosslinked high‐performance polymers have many industrial applications, but are difficult
to recycle or rework. A novel class of recyclable crosslinking Cu (II)‐metallo‐supramolecular …

Rubber-elasticity and electrochemical activity of iron (II) tris (bipyridine) crosslinked poly (dimethylsiloxane) networks

ZH Williams, ED Burwell, AE Chiomento, KJ Demsko… - Soft Matter, 2017 - pubs.rsc.org
2, 2′-Bipyridine-terminated poly (dimethylsiloxane) s (bpyPDMS) with number average
molecular weights, MN, of 3300, 6100, 26 200, and 50 000 g mol− 1 were synthesized …

Thermo-and redox-responsive dendronized polymer hydrogels

X Zhang, Y Yin, J Yan, W Li, A Zhang - Polymer Chemistry, 2018 - pubs.rsc.org
In order to combine dendritic structures and thermoresponsiveness within the field of metallo-
supramolecular chemistry, a novel type of smart hydrogel was prepared through ferrous ion …