Aluminosilicate zeolites such as UTD‐1 (structure shown) belong to a family of nanoporous
inorganic materials that find utility in catalysis, separation, and ion exchange. During the last …

Abstract Development of solventothermal methods in the intermediate‐temperature (100–
600° C) range has been motivated by current interest in the design of solid‐state …

Crystalline semiconducting sulfide and selenide zeolite analogs were synthesized that
possess four-connected, three-dimensional tetrahedral networks built from tetravalent (M4+ …

Although aluminosilicates and metal phosphates can form porous open-framework materials
such as zeolites, sulfide analogs usually form high-density phases because of the relatively …

The review covers structural aspects of the chemistry of ternary and quaternary
chalcogenidometalates of the heavier Group 14 (Ge, Sn, Pb) and 15 (As, Sb, Bi) elements …

Metal chalcogenide supertetrahedral clusters (MCSCs) are of significance for developing
crystalline porous framework materials and atomically precise cluster chemistry. Early …

Solid state reactions occur among solid reactants and are characterized by slow nucleation
and diffusion processes. Thus, high temperature is often required to promote the reactions to …

Face-capped octahedral [Re6Se8 (CN) 6] 3-/4-clusters are used in place of octahedral [M
(CN) 6] 3-/4-complexes for the synthesis of microporous Prussian blue type solids with …

Microporous materials have found extensive application as catalysts, ion-exchange media
and sorbents,. The discovery of mesoporous silica has opened the path to selective catalysis …

The self‐assembly of inorganic open framework structures has blossomed during the 1990s.
Following a short historical summary of the field, the main features of the major classes of …