Palladium-Catalyzed Carbonylations: Application in Complex Natural Product Total Synthesis and Recent Developments

HS Sims, M Dai - The Journal of Organic Chemistry, 2023 - ACS Publications
Carbon monoxide is a cheap and abundant C1 building block that can be readily
incorporated into organic molecules to rapidly build structural complexity. In this Perspective …

Contemporary approaches for amide bond formation

P Acosta‐Guzmán, A Ojeda‐Porras… - Advanced Synthesis …, 2023 - Wiley Online Library
Amide bond construction has garnered significant interest in recent decades due to amides
being one of the most prevalent functional groups among bioactive molecules. Out of the …

Photoinduced Five‐Component Radical Relay Aminocarbonylation of Alkenes

B Lu, Z Zhang, M Jiang, D Liang, ZW He… - Angewandte Chemie …, 2023 - Wiley Online Library
Radical single carbonylation reactions with CO constitute a direct and robust strategy toward
various carbonyl compounds from readily available chemicals, and have been extensively …

Switchable radical carbonylation by Philicity regulation

B Lu, M Xu, X Qi, M Jiang, WJ Xiao… - Journal of the American …, 2022 - ACS Publications
Carbonylation reactions involving CO as readily available C1 synthons have become one of
the most important tools for the construction of carbonyl compounds from feedstock …

Constructing multiple active sites in iron oxide catalysts for improving carbonylation reactions

S Liu, T Li, F Shi, H Ma, B Wang, X Dai, X Cui - Nature Communications, 2023 - nature.com
Surface engineering is a promising strategy to improve the catalytic activities of
heterogeneous catalysts. Nevertheless, few studies have been devoted to investigate the …

Copper‐Catalyzed 1, 2‐Dicarbonylative Cyclization of Alkenes with Alkyl Bromides via Radical Cascade Process

F Zhao, XW Gu, R Franke, XF Wu - Angewandte Chemie, 2022 - Wiley Online Library
Herein, we developed a new procedure on 1, 2‐dicarbonylative cyclization of 4‐aryl‐1‐
butenes with alkyl bromides. Using simple copper catalyst, two molecules of carbon …

Tuning the oxidative mono-or double-carbonylation of alkanes with CO by choosing a Co or Cu catalyst

L Lu, F Qiu, H Alhumade, H Zhang, A Lei - ACS Catalysis, 2022 - ACS Publications
The control of reaction selectivity is a core of organic synthesis, which requires the rational
design of the catalytic system. Carbonylation reactions involving CO, such as …

Manganese-Catalyzed Carbonylation of Unactivated Alkyl Bromides with Alkylidenecyclopropanes

PR Liu, MM Ji, JB Hu, JB Peng - ACS Catalysis, 2024 - ACS Publications
The transition-metal-catalyzed carbonylation reaction has emerged as a powerful method for
the construction of carbonyl compounds. However, very few examples have worked for the …

Recent Advances in Base‐Metal‐Catalyzed Carbonylation of Unactivated Alkyl Electrophiles

W Li, D Jiang, C Wang, LJ Cheng - Chinese Journal of …, 2023 - Wiley Online Library
Comprehensive Summary Transition metal‐catalyzed carbonylation reactions represent a
direct and atom‐economical approach to synthesize carbonyl compounds or their …

Recent advances in Cu-catalyzed carbonylation with CO

X Yan, L Fan, X Zhang, G Liu - Organic Chemistry Frontiers, 2022 - pubs.rsc.org
Transition metal-catalyzed carbonylation has emerged as a powerful and versatile strategy
for the efficient construction of complicated carbonyl-containing molecules from simple …