Vapochromic effect in switchable molecular-based spin crossover compounds

E Resines-Urien, E Fernandez-Bartolome… - Chemical Society …, 2023 - pubs.rsc.org
Coordination complexes based on transition metal ions displaying [Ar] 3d4–3d7 electronic
configurations can undergo the likely most spectacular switchable phenomena found in …

Old materials for new functions: recent progress on metal cyanide based porous materials

Y Xie, RB Lin, B Chen - Advanced Science, 2022 - Wiley Online Library
Cyanide is the simplest ligand with strong basicity to construct open frameworks including
some of the oldest compounds reported in the history of coordination chemistry. Cyanide …

Guest‐driven light‐induced spin change in an azobenzene loaded metal–organic framework

KP Xie, ZY Ruan, BH Lyu, XX Chen… - Angewandte …, 2021 - Wiley Online Library
Stimuli‐responsive materials that can be reversibly switched by light are of immense
interest. Among them, photo‐responsive spin crossover (SCO) complexes have great …

Spin Crossover-Assisted Modulation of Electron Transport in a Single-Crystal 3D Metal–Organic Framework

A Martinez-Martinez, E Resines-Urien… - Chemistry of …, 2023 - ACS Publications
Molecule-based spin crossover (SCO) materials display likely one of the most spectacular
switchable processes. The SCO involves reversible changes in their physicochemical …

Guest-Induced Multistep-to-One-Step Reversible Spin Transition with Enhanced Hysteresis in a 2D Hofmann Framework

DJ Mondal, A Mondal, A Paul, S Konar - Inorganic Chemistry, 2022 - ACS Publications
The interplay of host–guest interactions and controlled modulation of spin-crossover (SCO)
behavior is one of the most exploited topics regarding data storage, molecular sensing, and …

Two-Step Spin Crossover in Hofmann-Type Coordination Polymers [Fe(2-phenylpyrazine)2{M(CN)2}2] (M = Ag, Au)

VM Hiiuk, SI Shylin, DD Barakhtii, DM Korytko… - Inorganic …, 2022 - ACS Publications
Two 2D Hofmann-type complexes of the composition [Fe (Phpz) 2 {M (CN) 2} 2](where
Phpz= 2-phenylpyrazine; M= Ag, Au) have been synthesized, and their spin-crossover …

Spin crossover in FeII cyanometallic frameworks

OI Kucheriv, IO Fritsky, A Il'ya - Inorganica Chimica Acta, 2021 - Elsevier
Spin-crossover (SCO) compounds represent a huge class of switchable coordination
complexes that can change their electronic configurations under the influence of different …

A trinuclear {FeIII2FeII} complex involving both spin and non-spin transitions exhibits three-step and wide thermal hysteresis

XH Zhao, D Shao, JT Chen, DX Gan, J Yang… - Science China …, 2022 - Springer
The engineering of switchable molecules with magnetic multistability is lying on the cutting-
edge research topics for integrating multi-switches and ternary memory devices. Here we …

Spin‐State Modulation in FeII‐Based Hofmann‐Type Coordination Polymers: From Molecules to Materials

B Kumar, A Paul, DJ Mondal, P Paliwal… - The Chemical …, 2022 - Wiley Online Library
Spin crossover complexes that reversibly interconvert between two stable states imitate a
binary state of 0 and 1, delivering a promising possibility to address the data processing …

Coupling and decoupling of spin crossover and ferroelastic distortion: Unsymmetric hysteresis loop, phase diagram, and sequence of phases

E Collet, G Azzolina - Physical Review Materials, 2021 - APS
Spin-transition materials can exhibit thermal hysteresis due to cooperative elastic
interactions in between active molecular sites. It results from the coupling of the …