Molecular electronics: creating and bridging molecular junctions and promoting its commercialization

T Li, VK Bandari, OG Schmidt - Advanced Materials, 2023 - Wiley Online Library
Molecular electronics is driven by the dream of expanding Moore's law to the molecular level
for next‐generation electronics through incorporating individual or ensemble molecules into …

A Chemist's View on Electronic and Steric Effects of Surface Ligands on Plasmonic Metal Nanostructures

Y Kim, S Ji, JM Nam - Accounts of Chemical Research, 2023 - ACS Publications
Conspectus Plasmonic metal nanostructures have been extensively developed over the
past few decades because of their ability to confine light within the surfaces and manipulate …

Core-shell Ag@ C spheres derived from Ag-MOFs with tunable ligand exchanging phase inversion for electromagnetic wave absorption

Y Song, X Liu, Z Gao, Z Wang, Y Hu, K Yang… - Journal of Colloid and …, 2022 - Elsevier
It has become greatly significant to achieve structurally tunable electromagnetic wave
absorption materials (EMAs) derived from metal-organic frameworks (MOFs) via controllably …

Turn-off detection of Cr (III) with chelation enhanced fluorescence quenching effect by a naphthyl hydrazone Shiff base chemosensor

B Musikavanhu, Y Zhang, D Zhu, Z Xue, R Yuan… - … Acta Part A: Molecular …, 2022 - Elsevier
A thiophene substituted naphthyl hydrazone derivative NHT was synthesized using a one-
step route for the detection of trivalent chromium (Cr 3+). UV–visible absorption and …

The role of complexes of biogenic metals in living organisms

I Kostova - Inorganics, 2023 - mdpi.com
Biogenic metals and their various inorganic, organometallic, and coordination compounds
are comprehensively studied and extensively used in medical practice. Since the biogenic …

Formation and evolution of metallocene single-molecule circuits with direct gold-π links

B Lawson, P Zahl, MS Hybertsen… - Journal of the American …, 2022 - ACS Publications
Single-molecule circuits with group 8 metallocenes are formed without additional linker
groups in scanning tunneling microscope-based break junction (STMBJ) measurements at …

Manipulating Quantum Interference between σ and π Orbitals in Single-Molecule Junctions via Chemical Substitution and Environmental Control

HE Skipper, B Lawson, X Pan, V Degtiareva… - ACS …, 2023 - ACS Publications
Understanding and manipulating quantum interference (QI) effects in single molecule
junction conductance can enable the design of molecular-scale devices. Here we …

Cooperative Self-Assembly of Dimer Junctions Driven by π Stacking Leads to Conductance Enhancement

X Pan, E Montes, WY Rojas, B Lawson, H Vázquez… - Nano Letters, 2023 - ACS Publications
We demonstrate enhanced electronic transport through dimer molecular junctions, which
self-assemble between two gold electrodes in π–π stabilized binding configurations. Single …

Design principles based on intramolecular interactions for hydroxyl-functionalized covalent organic frameworks

L Zhang, SL Wang, GH Zhang, N Shen, H Chen… - Cell Reports Physical …, 2022 - cell.com
Designing covalent organic frameworks (COFs) with predetermined structures for uranium
capture is vital for energy and the environment, but it remains challenging for complex COFs …

Electronegativity equilibration

F Sessa, M Rahm - The Journal of Physical Chemistry A, 2022 - ACS Publications
Controlling the distribution of electrons in materials is the holy grail of chemistry and material
science. Practical attempts at this feat are common but are often reliant on simplistic …