Synthetic chemists have developed robust methods to synthesize discrete molecules, linear
and branched polymers, and disordered cross-linked networks. However, two-dimensional …

Copper (I)-catalyzed 1, 3-dipolar cycloaddition between organic azides and terminal
alkynes, commonly known as CuAAC or click chemistry, has been identified as one of the …

Topochemical polymerizations are solid-state reactions driven by the alignment of
monomers in the crystalline state. The molecular confinement in the monomer crystal lattice …

Azide-alkyne cycloaddition reaction is a very common organic reaction to synthesize
nitrogen-containing heterocycles. Once catalyzed by Cu (I) or Ru (II), it turns out to be a click …

Single-crystal polymers (SCPs) with unambiguous chemical structures at atomic-level
resolutions have attracted great attention. Obtaining precise structural information of these …

The synthesis of single-crystal, one-dimensional (1D) polymers is of great importance but a
formidable challenge. Herein, we report the synthesis of single-crystal 1D ladder polymers in …

The fascinating properties of single‐layer graphene isolated by mechanical exfoliation have
inspired extensive research efforts toward two‐dimensional (2D) materials. Layered …

Iodine is widely used as an antimicrobial reagent for water disinfection in the wilderness and
outer space, but residual iodine and iodide need to be removed for health reasons …

Designing and synthesizing flawless two-dimensional polymers (2D-Ps) via meticulous
molecular preorganization presents an intriguing yet challenging frontier in research. We …

A two-dimensional polymer (2DP) single crystal (T-2DP) with submillimeter size was
synthesized by single-crystal to single-crystal transformation based on photochemical [2+ 2] …