Orbital occupancy and spin polarization: from mechanistic study to rational design of transition metal-based electrocatalysts toward energy applications
VH Do, JM Lee - ACS nano, 2022 - ACS Publications
Over the past few decades, development of electrocatalysts for energy applications has
extensively transitioned from trial-and-error methodologies to more rational and directed …
extensively transitioned from trial-and-error methodologies to more rational and directed …
Spin‐related electron transfer and orbital interactions in oxygen electrocatalysis
Oxygen evolution and reduction reactions play a critical role in determining the efficiency of
the water cycling (H2O⇔ H2+ 1 2 O2), in which the hydrogen serves as the energy carrier …
the water cycling (H2O⇔ H2+ 1 2 O2), in which the hydrogen serves as the energy carrier …
Ferromagnetic single-atom spin catalyst for boosting water splitting
Heterogeneous single-atom spin catalysts combined with magnetic fields provide a powerful
means for accelerating chemical reactions with enhanced metal utilization and reaction …
means for accelerating chemical reactions with enhanced metal utilization and reaction …
Spin-Polarized Photocatalytic CO2 Reduction of Mn-Doped Perovskite Nanoplates
“Spin” has been recently reported as an important degree of electronic freedom to improve
the performance of electrocatalysts and photocatalysts. This work demonstrates the …
the performance of electrocatalysts and photocatalysts. This work demonstrates the …
Mechanistic insight into the active centers of single/dual-atom Ni/Fe-based oxygen electrocatalysts
Single-atom catalysts with maximum metal utilization efficiency show great potential for
sustainable catalytic applications and fundamental mechanistic studies. We here provide a …
sustainable catalytic applications and fundamental mechanistic studies. We here provide a …
Spin‐polarization strategy for enhanced acidic oxygen evolution activity
L Li, J Zhou, X Wang, J Gracia, M Valvidares… - Advanced …, 2023 - Wiley Online Library
Spin‐polarization is known as a promising way to promote the anodic oxygen evolution
reaction (OER), since the intermediates and products endow spin‐dependent behaviors, yet …
reaction (OER), since the intermediates and products endow spin‐dependent behaviors, yet …
Spin-polarized oxygen evolution reaction under magnetic field
The oxygen evolution reaction (OER) is the bottleneck that limits the energy efficiency of
water-splitting. The process involves four electrons' transfer and the generation of triplet …
water-splitting. The process involves four electrons' transfer and the generation of triplet …
Spin pinning effect to reconstructed oxyhydroxide layer on ferromagnetic oxides for enhanced water oxidation
Producing hydrogen by water electrolysis suffers from the kinetic barriers in the oxygen
evolution reaction (OER) that limits the overall efficiency. With spin-dependent kinetics in …
evolution reaction (OER) that limits the overall efficiency. With spin-dependent kinetics in …
Spin-related symmetry breaking induced by half-disordered hybridization in BixEr2-xRu2O7 pyrochlores for acidic oxygen evolution
While acidic oxygen evolution reaction plays a critical role in electrochemical energy
conversion devices, the sluggish reaction kinetics and poor stability in acidic electrolyte …
conversion devices, the sluggish reaction kinetics and poor stability in acidic electrolyte …
Electrochemistry in magnetic fields
S Luo, K Elouarzaki, ZJ Xu - Angewandte Chemie International …, 2022 - Wiley Online Library
Developing new strategies to advance the fundamental understanding of electrochemistry is
crucial to mitigating multiple contemporary technological challenges. In this regard …
crucial to mitigating multiple contemporary technological challenges. In this regard …