Ylide ligands

EP Urriolabeitia - Transition Metal Complexes of Neutral eta1-Carbon …, 2010 - Springer
The use of ylides of P, N, As, or S as ligands toward transition metals is still a very active
research area in organometallic chemistry. This fact is mainly due to the nucleophilic …

Organometallic palladium complexes with a water-soluble iminophosphorane ligand as potential anticancer agents

M Carreira, R Calvo-Sanjuan, M Sanau, I Marzo… - …, 2012 - ACS Publications
The synthesis and characterization of a new water-soluble iminophosphorane ligand TPA
NC (O)-2BrC6H4 (1, C, N-IM; TPA= 1, 3, 5-triaza-7-phosphaadamantane) is reported …

Chasing C,C‐Palladacycles

JA García‐López… - European Journal of …, 2021 - Wiley Online Library
The different approaches for the synthesis of C, C‐palladacycles are reviewed in this
manuscript. These species hold a bidentate ligand that chelates the Pd atom through two C …

Luminescent iminophosphorane gold, palladium and platinum complexes as potential anticancer agents

M Frik, J Jiménez, V Vasilevski, M Carreira… - Inorganic chemistry …, 2014 - pubs.rsc.org
A series of coordination gold (III), palladium (II), and platinum (II) complexes with a
luminescent iminophosphorane ligand derived from 8-aminoquinoline [Ph3PN–C9H6N](1) …

Potent cyclometallated Pd (II) antitumor complexes bearing α-amino acids: synthesis, structural characterization, DNA/BSA binding, cytotoxicity and molecular …

S Abedanzadeh, K Karami, M Rahimi, M Edalati… - Dalton …, 2020 - pubs.rsc.org
A rational approach was adopted to design high-potential metal-based antitumor agents. A
series of organometallic Pd (II) complexes with a general formula of [Pd {κ2 (C, C)-[(C6H4-2) …

Palladium (II) pincer complexes of a C, C, C-NHC, diphosphonium bis (ylide) ligand

R Taakili, C Lepetit, C Duhayon, DA Valyaev… - Dalton …, 2019 - pubs.rsc.org
A new family of pincer palladium (II) complexes bearing an electron-rich C, C, C-NHC,
diphosphonium bis (ylide) ligand of LX2-type was prepared through the dual N …

Synthesis and characterization of new Pd (II) non-symmetrical pincer complexes derived from thioether functionalized iminophosphoranes. Evaluation of their catalytic …

S Ramirez-Rave, F Estudiante-Negrete… - Journal of …, 2014 - Elsevier
Abstract The iminophosphorane ligands (Ph 3 Pdouble bondNC 6 H 4 SR)[R= CH 3 (1) and
C 6 H 5 (2)] were easily synthesized from triphenylphosphine and 2-(methylthio) aniline or 2 …

[图书][B] Organophosphorus Chemistry: Volume 35

CD Hall, N Bricklebank, J Van De Grampel, M Migaud… - 2006 - books.google.com
Organophosphorus Chemistry provides a comprehensive annual review of the literature.
Coverage includes phosphines and their chalcogenides, phosphonium salts, low …

Regioselective Orthopalladation of (Z)-2-Aryl-4-Arylidene-5(4H)-Oxazolones: Scope, Kinetico-Mechanistic, and Density Functional Theory Studies of the C–H Bond …

GD Roiban, E Serrano, T Soler, G Aullón… - Inorganic …, 2011 - ACS Publications
Orthopalladated complexes derived from (Z)-2-aryl-4-arylidene-5 (4 H)-oxazolones have
been prepared by reaction of the oxazolone with palladium acetate in acidic medium. The …

Extending the application scope of organophosphorus (V) compounds in palladium (II) pincer chemistry

DV Aleksanyan, SG Churusova, ZS Klemenkova… - …, 2019 - ACS Publications
1-Dimethylthiocarbamoyloxy-3-diphenylphosphinobenzene was used as a key precursor for
the synthesis of a whole series of organophosphorus (V) pincer ligands combining …