Molecular photoswitching in confined spaces

AB Grommet, LM Lee, R Klajn - Accounts of Chemical Research, 2020 - ACS Publications
Conspectus In nature, light is harvested by photoactive proteins to drive a range of biological
processes, including photosynthesis, phototaxis, vision, and ultimately life …

Azobenzene isomerization in condensed matter: lessons for the design of efficient light-responsive soft-matter systems

LW Giles, CFJ Faul, RF Tabor - Materials Advances, 2021 - pubs.rsc.org
Azobenzene-based materials have found applications in a wide variety of systems as a
convenient method to induce photo-responsive behaviour through facile trans (E) to cis (Z) …

Manipulating azobenzene photoisomerization through strong light–molecule coupling

J Fregoni, G Granucci, E Coccia, M Persico… - Nature …, 2018 - nature.com
The formation of hybrid light–molecule states (polaritons) offers a new strategy to manipulate
the photochemistry of molecules. To fully exploit its potential, one needs to build a toolbox of …

Molecular factors controlling the isomerization of azobenzenes in the cavity of a flexible coordination cage

L Pesce, C Perego, AB Grommet, R Klajn… - Journal of the …, 2020 - ACS Publications
Photoswitchable molecules are employed for many applications, from the development of
active materials to the design of stimuli-responsive molecular systems and light-powered …

An azobenzene-based single-component supramolecular polymer responsive to multiple stimuli in water

E Fuentes, M Gerth, JA Berrocal, C Matera… - Journal of the …, 2020 - ACS Publications
One of the most appealing features of supramolecular assemblies is their ability to respond
to external stimuli due to their noncovalent nature. This provides the opportunity to gain …

How defects control the out-of-equilibrium dissipative evolution of a supramolecular tubule

D Bochicchio, S Kwangmettatam, T Kudernac… - ACS …, 2019 - ACS Publications
Supramolecular architectures that work out-of-equilibrium or that can change in specific
ways when absorbing external energy are ubiquitous in nature. Gaining the ability to create …

Photosensitive cationic azobenzene surfactants: Thermodynamics of hydration and the complex formation with poly (methacrylic acid)

M Montagna, O Guskova - Langmuir, 2018 - ACS Publications
In this computational work, we investigate the photosensitive cationic surfactants with the
trimethylammonium or polyamine hydrophilic head and the azobenzene-containing …

Steric charge

S Liu, L Liu, D Yu, C Rong, T Lu - Physical Chemistry Chemical …, 2018 - pubs.rsc.org
The steric effect is one of the most widely used chemical concepts in chemistry, yet a
generally accepted implementation of its formulation and quantification from a theoretical …

Visible Light Induced Exciton Dynamics and trans-to-cis Isomerization in Azobenzene Aggregates: Insights from Surface Hopping/Semiempirical Configuration …

E Titov - ACS omega, 2024 - ACS Publications
Assemblies of photochromic molecules feature exciton states, which govern photochemical
and photophysical processes in multichromophoric systems. Understanding the …

Computational design of a molecular triple photoswitch for wavelength-selective control

C Yang, C Slavov, HA Wegner, J Wachtveitl… - Chemical …, 2018 - pubs.rsc.org
A small single molecule with multiple photoswitchable subunits, selectively and
independently controllable by light of different wavelengths, is highly attractive for …