Iron photoredox catalysis–past, present, and future
Photoredox catalysis of organic reactions driven by iron has attracted substantial attention
throughout recent years, due to potential environmental and economic benefits. In this …
throughout recent years, due to potential environmental and economic benefits. In this …
The great strides of iron photosensitizers for contemporary organic photoredox catalysis: On our way to the holy grail?
The scarcity of 2 nd and 3 rd row transition metals such as ruthenium, iridium, rhodium and
osmium, coupled with a global desire for sustainable chemistry has led to the resurgence of …
osmium, coupled with a global desire for sustainable chemistry has led to the resurgence of …
Photoredox catalysis via consecutive 2 LMCT-and 3 MLCT-excitation of an Fe (iii/ii)–N-heterocyclic carbene complex
Fe–N-heterocyclic carbene (NHC) complexes attract increasing attention as
photosensitisers and photoredox catalysts. Such applications generally rely on sufficiently …
photosensitisers and photoredox catalysts. Such applications generally rely on sufficiently …
Ferrous and ferric complexes with cyclometalating N-heterocyclic carbene ligands: a case of dual emission revisited
Iron N-heterocyclic carbene (FeNHC) complexes with long-lived charge transfer states are
emerging as a promising class of photoactive materials. We have synthesized [FeII (ImP) …
emerging as a promising class of photoactive materials. We have synthesized [FeII (ImP) …
Electronic Structures and Photoredox Chemistry of Tungsten (0) Arylisocyanides
AT Barth, J Fajardo Jr, W Sattler… - Accounts of Chemical …, 2023 - ACS Publications
Conspectus The high energy barriers associated with the reaction chemistry of inert
substrates can be overcome by employing redox-active photocatalysts. Research in this …
substrates can be overcome by employing redox-active photocatalysts. Research in this …
Factors that Impact Photochemical Cage Escape Yields
The utilization of visible light to mediate chemical reactions in fluid solutions has
applications that range from solar fuel production to medicine and organic synthesis. These …
applications that range from solar fuel production to medicine and organic synthesis. These …
Spectroscopic Techniques to Unravel Mechanistic Details in Light‐Induced Transformations and Photoredox Catalysis
The rapid development of photo (redox) catalysis within the last decades is remarkable to
the extent that the utilization of light‐driven processes in organic chemistry has become a …
the extent that the utilization of light‐driven processes in organic chemistry has become a …
[HTML][HTML] A protocol for determining cage-escape yields using nanosecond transient absorption spectroscopy
Here, we present a protocol for the determination of cage-escape yields following excited-
state electron transfer between a photosensitizer and a quencher. We describe steps for …
state electron transfer between a photosensitizer and a quencher. We describe steps for …
Investigation of the Excited-State Electron Transfer and Cage Escape Yields Between Halides and a Fe (III) Photosensitizer
S De Kreijger, A Ripak, B Elias… - Journal of the American …, 2024 - ACS Publications
Excited-state quenching and reduction of [Fe (phtmeimb) 2]+, where phtmeimb is phenyl [tris
(3-methyl-imidazolin-2-ylidene)] borate, with iodide, bromide, and chloride were studied in …
(3-methyl-imidazolin-2-ylidene)] borate, with iodide, bromide, and chloride were studied in …
Competing dynamics of intramolecular deactivation and bimolecular charge transfer processes in luminescent Fe (III) N-heterocyclic carbene complexes
NW Rosemann, L Lindh, IB Losada, S Kaufhold… - Chemical …, 2023 - pubs.rsc.org
Steady state and ultrafast spectroscopy on [FeIII (phtmeimb) 2] PF6 (phtmeimb= phenyl (tris
(3-methylimidazol-2-ylidene)) borate) was performed over a broad range of temperatures …
(3-methylimidazol-2-ylidene)) borate) was performed over a broad range of temperatures …