Compendium of cycloaddition reactions under high pressure

K Matsumoto, H Hamana, H Iida - Helvetica chimica acta, 2005 - Wiley Online Library
High‐pressure technology finds its major application in the field of organic synthesis,
especially for cycloaddition reactions. The aim of this article is to review all examples of high …

Enantioselective Total Syntheses of (−)-Taiwaniaquinone H and (−)-Taiwaniaquinol B by Iridium-Catalyzed Borylation and Palladium-Catalyzed Asymmetric α …

X Liao, LM Stanley, JF Hartwig - Journal of the American Chemical …, 2011 - ACS Publications
We report a concise, enantioselective total synthesis of (−)-taiwaniaquinone H and the first
enantioselective total synthesis of (−)-taiwaniaquinol B by a route that includes asymmetric …

Organoselenium‐catalyzed Baeyer–Villiger oxidation of α, β‐unsaturated ketones by hydrogen peroxide to access vinyl esters

X Zhang, J Ye, L Yu, X Shi, M Zhang… - Advanced Synthesis …, 2015 - Wiley Online Library
By carefully screening the organoselenium pre‐catalysts and optimizing the reaction
conditions, simple dibenzyl diselenide was found to be the best pre‐catalyst for Baeyer …

Total synthesis of (−)-3-oxoisotaxodione

SJ Plamondon, JL Gleason - Organic Letters, 2022 - ACS Publications
The first total synthesis of the abietaquinone methide diterpenoid (−)-3-oxoisotaxodione is
reported. The key enabling step is the use of a chiral bicyclic hydrazide as an organocatalyst …

Organoselenium-catalyzed selectivity-switchable oxidation of β-ionone

L Yu, Z Bai, X Zhang, X Zhang, Y Ding… - Catalysis Science & …, 2016 - pubs.rsc.org
Catalyzed by organoselenium compounds, β-ionone was easily oxidized by H2O2 under
mild and clean conditions. We were very surprised to find that the reaction selectivity was …

Programmed polyene cyclization enabled by chromophore disruption

MM Solans, VS Basistyi, JA Law… - Journal of the …, 2022 - ACS Publications
A new polyene cyclization strategy exploiting β-ionyl derivatives was developed.
Photoinduced deconjugation of the extended π-system within these chromophores unveils a …

Effect of abietane diterpenes from Plectranthus grandidentatus on the growth of human cancer cell lines

CG Marques, M Pedro, MFA Simões… - Planta …, 2002 - thieme-connect.com
Five known abietane diterpenes, fatty acid esters of 7α-acyloxy-6β-hydroxyroyleanone (1),
grandidone A (2), 7α-acetoxy-6β-hydroxyroyleanone (3), 6β, 7α-dihydroxyroyleanone (4) …

Ultrasound-promoted cycloadditions in the synthesis of Salvia miltiorrhiza abietanoid o-quinones

J Lee, JK Snyder - The Journal of Organic Chemistry, 1990 - ACS Publications
The ultrasound-promoted Diels-Alder reaction of 3-methyl-4, 5-benzofurandione with
appropriately substituted vinylcyclohexenes has led to the synthesis of tanshinone IIA …

Regioselective routes towards 14-hydroxyabietane diterpenes. A formal synthesis of immunosuppressant (−)-triptolide from (+)-abietic acid

E Alvarez-Manzaneda, R Chahboun, F Bentaleb… - Tetrahedron, 2007 - Elsevier
Two procedures to introduce an oxygenated function into the C-14 of abietane diterpenes
with complete regioselectivity have been developed. Utilizing these, the synthesis of the …

13C NMR Data for abieta‐8,11,13‐triene diterpenoids

JMMD Corral, M Gordaliza, MA Salinero… - Magnetic …, 1994 - Wiley Online Library
<sup>13</sup>C NMR Data for abietaâ•’8,11,13â•’triene diterpenoids Page 1 MAGNETIC
RESONANCE IN CHEMISTRY, VOL. 32, 774-781 (1994) Reference Data Review I3C NMR Data …