Probing surface properties of organic molecular layers by scanning tunneling microscopy

H Wu, G Li, J Hou, K Sotthewes - Advances in colloid and interface science, 2023 - Elsevier
In view of the relevance of organic thin layers in many fields, the fundamentals, growth
mechanisms, and dynamics of thin organic layers, in particular thiol-based self-assembled …

Control of molecule-based transport for future molecular devices

S Karthäuser - Journal of Physics: Condensed Matter, 2010 - iopscience.iop.org
In this review, possibilities to modify intentionally the electronic transport properties of
metal/molecule/metal devices (MMM devices) are discussed. Here especially the influence …

[HTML][HTML] Controlling the direction of rectification in a molecular diode

L Yuan, N Nerngchamnong, L Cao, H Hamoudi… - Nature …, 2015 - nature.com
A challenge in molecular electronics is to control the strength of the molecule–electrode
coupling to optimize device performance. Here we show that non-covalent contacts between …

Molecular rectification in metal− SAM− metal oxide− metal junctions

CA Nijhuis, WF Reus… - Journal of the American …, 2009 - ACS Publications
This Article compares the ability of self-assembled monolayers (SAMs) of alkanethiolates
with ferrocene (Fc) head groups (SC11Fc), and SAMs of alkanethiolates lacking the Fc …

Charge transport and rectification in arrays of SAM-based tunneling junctions

CA Nijhuis, WF Reus, JR Barber, MD Dickey… - Nano …, 2010 - ACS Publications
This paper describes a method of fabrication that generates small arrays of tunneling
junctions based on self-assembled monolayers (SAMs); these junctions have liquid-metal …

Mechanism of rectification in tunneling junctions based on molecules with asymmetric potential drops

CA Nijhuis, WF Reus… - Journal of the American …, 2010 - ACS Publications
This paper proposes a mechanism for the rectification of current by self-assembled
monolayers (SAMs) of alkanethiolates with Fc head groups (SC11Fc) in SAM-based …

A molecular diode with a statistically robust rectification ratio of three orders of magnitude

L Yuan, R Breuer, L Jiang, M Schmittel, CA Nijhuis - Nano letters, 2015 - ACS Publications
This paper describes a molecular diode with high, statistically robust, rectification ratios R of
1.1× 103. These diodes operate with a new mechanism of charge transport based on …

Transition from direct to inverted charge transport Marcus regions in molecular junctions via molecular orbital gating

L Yuan, L Wang, AR Garrigues, L Jiang… - Nature …, 2018 - nature.com
Solid-state molecular tunnel junctions are often assumed to operate in the Landauer regime,
which describes essentially activationless coherent tunnelling processes. In solution, on the …

A molecular half-wave rectifier

CA Nijhuis, WF Reus, AC Siegel… - Journal of the American …, 2011 - ACS Publications
This paper describes the performance of junctions based on self-assembled monolayers
(SAMs) as the functional element of a half-wave rectifier (a simple circuit that converts, or …

Single-Molecule Observation of Redox Reactions Enabled by Rigid and Isolated Tripodal Molecules

Y Kobayashi, Y Yokota, RA Wong, M Hong… - The Journal of …, 2022 - ACS Publications
Tracking various chemical reactions, including electrochemical and photochemical reactions
at the single-molecule level, is expected to yield a great deal of knowledge from both …