Characterization of agostic interactions in theory and computation
M Lein - Coordination Chemistry Reviews, 2009 - Elsevier
Agostic interactions are covalent intramolecular interactions between an electron deficient
metal and a σ-bond in close geometrical proximity to the metal atom. While the classic cases …
metal and a σ-bond in close geometrical proximity to the metal atom. While the classic cases …
USc2C2 and USc2NC Clusters with U–C Triple Bond Character Stabilized Inside Fullerene Cages
H Jiang, X Yu, M Guo, YR Yao, Q Meng… - Journal of the …, 2023 - ACS Publications
The chemistry of f-block metal–carbon multiple bonds is underdeveloped compared to well-
established carbene complexes of the d-block transition metals. Herein, we report two new …
established carbene complexes of the d-block transition metals. Herein, we report two new …
Metal–ligand multiple bonding in uranium: structure and reactivity
TW Hayton - Dalton Transactions, 2010 - pubs.rsc.org
There is a growing interest in uranium coordination chemistry, particularly as it relates to
metal–ligand multiple bonding, and in the last decade significant progress has been made …
metal–ligand multiple bonding, and in the last decade significant progress has been made …
Raman spectroscopy of cementitious materials
L Black - Spectrosc. Prop. Inorg. Organomet. Compd, 2009 - books.google.com
This review aims to look at the development of Raman spectroscopy as applied to the field of
cement science. Starting with a historical overview, it then considers the spectra of cements …
cement science. Starting with a historical overview, it then considers the spectra of cements …
Synthesis of a Uranium(VI)-Carbene: Reductive Formation of Uranyl(V)-Methanides, Oxidative Preparation of a [R2CUO]2+ Analogue of the [OUO]2+ Uranyl Ion (R = Ph2PNSiMe3), and …
DP Mills, OJ Cooper, F Tuna, EJL McInnes… - Journal of the …, 2012 - ACS Publications
We report attempts to prepare uranyl (VI)-and uranium (VI) carbenes utilizing deprotonation
and oxidation strategies. Treatment of the uranyl (VI)-methanide complex [(BIPMH) UO2Cl …
and oxidation strategies. Treatment of the uranyl (VI)-methanide complex [(BIPMH) UO2Cl …
The U C Double Bond: Synthesis and Study of Uranium Nucleophilic Carbene Complexes
T Cantat, T Arliguie, A Noël, P Thuéry… - Journal of the …, 2009 - ACS Publications
Treatment of U (BH4) 4 with 1 or 3 equiv of Li2 (SCS)· 1.5 Et2O, 1, afforded the actinide
carbene complexes U (μ-SCS) 3 [U (BH4) 3] 2 (4) and U (μ-SCS) 3 [Li (Et2O)] 2 (6) …
carbene complexes U (μ-SCS) 3 [U (BH4) 3] 2 (4) and U (μ-SCS) 3 [Li (Et2O)] 2 (6) …
[HTML][HTML] Synthesis and electronic structure analysis of the actinide allenylidenes,[{(NR 2) 3} An (CCCPh 2)]−(An= U, Th; R= SiMe 3)
GT Kent, X Yu, G Wu, J Autschbach, TW Hayton - Chemical Science, 2021 - pubs.rsc.org
The reaction of [AnCl (NR2) 3](An= U, Th, R= SiMe3) with in situ generated lithium-3, 3-
diphenylcyclopropene results in the formation of [{(NR2) 3} An (CHCCPh2)](An= U, 1; Th, 2) …
diphenylcyclopropene results in the formation of [{(NR2) 3} An (CHCCPh2)](An= U, 1; Th, 2) …
[HTML][HTML] Double dative bond between divalent carbon (0) and uranium
Dative bonds between p-and d-block atoms are common but species containing a double
dative bond, which donate two-electron pairs to the same acceptor, are far less common …
dative bond, which donate two-electron pairs to the same acceptor, are far less common …
[PDF][PDF] Uranium–Carbon Multiple Bonding: Facile Access to the Pentavalent Uranium Carbene [U{C(PPh2NSiMe3)2}(Cl)2(I)] and Comparison of UVC and UIV …
OJ Cooper, DP Mills, J McMaster, F Moro… - Angewandte …, 2011 - academia.edu
Compared to the extensive investigations of d-block metal–ligand multiple bonding and
reactivity,[1] the corresponding field of f-block chemistry is underdeveloped.[2, 3] For …
reactivity,[1] the corresponding field of f-block chemistry is underdeveloped.[2, 3] For …
Synthesis of a phosphorano-stabilized U (IV)-carbene via one-electron oxidation of a U (III)-ylide adduct
S Fortier, JR Walensky, G Wu… - Journal of the American …, 2011 - ACS Publications
Addition of the Wittig reagent Ph3P CH2 to the U (III) tris (amide) U (NR2) 3 (R= SiMe3)
generates a mixture of products from which the U (IV) complex U CHPPh3 (NR2) 3 (2) can …
generates a mixture of products from which the U (IV) complex U CHPPh3 (NR2) 3 (2) can …