Azines, such as pyridines, quinolines, pyrimidines, and pyridazines, are widespread
components of pharmaceuticals. Their occurrence derives from a suite of physiochemical …

Photoredox chemistry with organic or transition metal agents has been reviewed in earlier
years, but such is the pace of progress that we will overlap very little with earlier …

Reactions that involve the addition of carbon‐centered radicals to basic heteroarenes,
followed by formal hydrogen atom loss, have become widely known as Minisci‐type …

Decarboxylative C− H functionalization reactions are highly attractive methods for forging
carbon–carbon bonds considering their inherent step‐and atom‐economical features and …

Herein, a metal-and photosensitizer-free protocol has been developed for decarboxylative C–
H (amino) alkylation of heteroarenes using carboxylic acids as the (amino) alkylating …

Over the last several years, radical‐mediated decarboxylative cross‐coupling reactions
employing alkyl carboxylic acids have emerged as a powerful tool for the regiospecific …

We report a method for the electrochemical deuteration of α, β‐unsaturated carbonyl
compounds under catalyst‐and external‐reductant‐free conditions, with deuteration rates as …

A facile transition-metal-free decarboxylative radical coupling reaction of α, α-
difluoroarylacetic acids with quinoxalin-2 (1H)-ones has been developed. This methodology …

A direct intermolecular decarboxylative Giese amidation reaction from bench stable, non-
toxic and environmentally benign oxamic acids has been developed, which allows for easy …

C–H late-stage functionalization has gradually become a powerful approach for the rapid
optimization of lead compounds' bioactivity. Significant advances in this field have been …