Diazirines are among the smallest photoreactive groups that form a reactive carbene upon
light irradiation. This feature has been widely utilized in photoaffinity labeling to study ligand …

Arylnitrenes are very reactive and short-lived intermediates commonly generated by
decomposition of aryl azides. Although other arylnitrene precursors are known1 and their …

The second edition of this best-selling handbook is bigger, more comprehensive, and now
completely current. In addition to thorough updates to the discussions featured in the first …

The intra-and intermolecular chemistry of phenylnitrene (PhN), its singlet− triplet energy
separation, and its electronic spectra are interpreted with the aid of ab initio molecular orbital …

Seven membered heterocyclic Azepine and its derivatives have great pharmacological and
therapeutic implications. In this review, the literature of the last fifty years has been exploited …

One of the major events occurring at biological interfaces is the specific recognition of
bioactive ligands by their receptor proteins. The elucidation of interacting partners is an …

As a result of recent developments in molecular biology, the investigation of biofunctional
machinery at ligand‐accepting interfaces has become one of the challenging and important …

Chemical labeling of proteins in live cells helps to probe their native functions in biological
systems. Aryl azides are chemically inert under physiological conditions, but they are …

The elucidation of substrate–protein interactions is an important component of the drug
development process. Due to the complexity of native cellular environments, elucidating …

In 1984 we assumed4a that ring expansion of 2S had a normal pre-exponential factor of
1012-14 s-1 and that intersystem crossing (ISC) of 2S had zero activation energy (Ea) and a …