The 'acac method'for the synthesis of coordination and organometallic compounds: Synthesis of gold complexes
J Vicente, MT Chicote - Coordination Chemistry Reviews, 1999 - Elsevier
In this review we show the synthetic utility of acetylacetonatogold complexes as reagents for
preparing gold (III) complexes with C, N and O donor ligands and gold (I) complexes with …
preparing gold (III) complexes with C, N and O donor ligands and gold (I) complexes with …
The Chemistry of cyclometallated gold (III) complexes with C, N-donor ligands
W Henderson - Advances in Organometallic Chemistry, 2006 - Elsevier
Publisher Summary This chapter describes the chemistry of gold (III) complexes containing
cycloaurated ligands, with particular emphasis on the synthesis and reactivity of these …
cycloaurated ligands, with particular emphasis on the synthesis and reactivity of these …
Cyclometallated gold (III) hydroxides as versatile synthons for Au–N, Au–C complexes and luminescent compounds
DA Roşca, DA Smith, M Bochmann - Chemical Communications, 2012 - pubs.rsc.org
The gold (III) hydroxide κ3-(C∧ N∧ C)* Au (OH) reacts with C–H and N–H compounds and
arylboronic acids to produce a range of perfluoroaryls, N-heterocyclic and alkynyl …
arylboronic acids to produce a range of perfluoroaryls, N-heterocyclic and alkynyl …
[HTML][HTML] Stoichiometric to catalytic reactivity of the aryl cycloaurated species with arylboronic acids: insight into the mechanism of gold-catalyzed oxidative C (sp 2)–H …
Q Wu, C Du, Y Huang, X Liu, Z Long, F Song… - Chemical Science, 2015 - pubs.rsc.org
Based on the well-defined five-membered aryl gold (III) complexes,[Au (tpy) X2](3a and 3b)
and [AuBr (Ph)(tpy)](7), as well as the aryl gold (III) complex [AuCl2 (Ph)(tpy)](8)(tpy= 2-(o …
and [AuBr (Ph)(tpy)](7), as well as the aryl gold (III) complex [AuCl2 (Ph)(tpy)](8)(tpy= 2-(o …
A Bis(ortho-amine)aryl−Gold(I) Compound as an Efficient, Nontoxic, Arylating Reagent
A novel strategy for the synthesis of bis (ortho-amine) chelated monoanionic bisaminoaryl−
metal complexes is presented. This method constitutes the exchange of a monoanionic …
metal complexes is presented. This method constitutes the exchange of a monoanionic …
The chemistry of gold
MC Gimeno - … Gold Chemistry: Gole-Metal Interactions and …, 2008 - Wiley Online Library
Gold was discovered as shining yellow nuggets and is undoubtedly the first metal known to
early civilizations. The symbol derives from the Latin word aurum, which is related to the …
early civilizations. The symbol derives from the Latin word aurum, which is related to the …
Synthesis and characterization of gold (III) adducts and cyclometallated derivatives with 2-substituted pyridines. Crystal structure of [Au {NC 5 H 4 (CMe 2 C 6 H 4)-2} …
M AgostinaáCinellu - Journal of the Chemical Society, Dalton …, 1995 - pubs.rsc.org
The 2-benzylpyridines HL [NC5H4-(CH2Ph)-2,-(CHMePh)-2 and (CMe2Ph)-2] reacted with
AuCl3· 2H2O or Na [AuCl4] to give adducts [Au (HL) Cl3] or cyclometallated derivatives …
AuCl3· 2H2O or Na [AuCl4] to give adducts [Au (HL) Cl3] or cyclometallated derivatives …
2-[(Dimethylamino) methyl] phenylgold (III) complexes
J Vicente, MT Chicote, MD Bermúdez - Journal of organometallic chemistry, 1984 - Elsevier
Abstract [Hg (2-C 6 H 4 CH 2 NMe 2) Cl] reacts with Me 4 N [AuCl 4] or with [AuCl 3 (tht)](tht=
tetrahydrothiophene) in the presence of Me 4 NCl to give [Au (2-C 6 H 4 CH 2 NMe 2) Cl 2] …
tetrahydrothiophene) in the presence of Me 4 NCl to give [Au (2-C 6 H 4 CH 2 NMe 2) Cl 2] …
Recent Development in arylgold chemistry
R Usón, A Laguna - Coordination chemistry reviews, 1986 - Elsevier
The first arylgold compounds synthesised in 1931 [la] were well characterised as late as
1960 [lb]. During the sixties, this area developed only slowly and the review [2] by Armer and …
1960 [lb]. During the sixties, this area developed only slowly and the review [2] by Armer and …
Synthesis of intermediates in the C–H activation of acetone with 2-phenylazophenylgold (III) complexes and in the C–C coupling of aryl groups from diarylgold (III) …
J Vicente, MD Bermúdez, J Escribano… - Journal of the …, 1990 - pubs.rsc.org
The complex [[graphic omitted] Ph-2) Cl2] reacts with [HgR2](R= C6H4NO2-2 or C6F5) and
NMe4Cl (2: 1: 2) to give [[graphic omitted] Ph-2)(R) Cl][R= C6H4NO2-2,(1); or C6F5 (2)] …
NMe4Cl (2: 1: 2) to give [[graphic omitted] Ph-2)(R) Cl][R= C6H4NO2-2,(1); or C6F5 (2)] …