Recent advances in triplet–triplet annihilation upconversion and singlet fission, towards solar energy applications
Solar energy is an ample renewable energy resource, with photovoltaic (PV) technology
enabling a direct route from light to electricity. Currently, PVs are limited in photon …
enabling a direct route from light to electricity. Currently, PVs are limited in photon …
Theoretical modeling of singlet fission
D Casanova - Chemical reviews, 2018 - ACS Publications
Singlet fission is a photophysical reaction in which a singlet excited electronic state splits
into two spin-triplet states. Singlet fission was discovered more than 50 years ago, but the …
into two spin-triplet states. Singlet fission was discovered more than 50 years ago, but the …
Unconventional singlet fission materials
Singlet fission (SF) is a photophysical downconversion pathway, in which a singlet excitation
transforms into two triplet excited states. As such, it constitutes an exciton multiplication …
transforms into two triplet excited states. As such, it constitutes an exciton multiplication …
Harnessing singlet exciton fission to break the Shockley–Queisser limit
Singlet exciton fission is a carrier multiplication process in organic semiconductors that
generates two electron–hole pairs for each photon absorbed. Singlet fission occurs on sub …
generates two electron–hole pairs for each photon absorbed. Singlet fission occurs on sub …
Strongly exchange-coupled triplet pairs in an organic semiconductor
From biological complexes to devices based on organic semiconductors, spin interactions
play a key role in the function of molecular systems. For instance, triplet-pair reactions …
play a key role in the function of molecular systems. For instance, triplet-pair reactions …
Using molecular design to enhance the coherence time of quintet multiexcitons generated by singlet fission in single crystals
Multiexciton quintet states, 5 (TT), photogenerated in organic semiconductors using singlet
fission (SF), consist of four quantum entangled spins, promising to enable new applications …
fission (SF), consist of four quantum entangled spins, promising to enable new applications …
The entangled triplet pair state in acene and heteroacene materials
Entanglement of states is one of the most surprising and counter-intuitive consequences of
quantum mechanics, with potent applications in cryptography and computing. In organic …
quantum mechanics, with potent applications in cryptography and computing. In organic …
Photochemical upconversion
Photochemical upconversion is a process whereby two lower-energy photons are converted
into a higher-energy photon by sensitized triplet–triplet annihilation. While recent interest in …
into a higher-energy photon by sensitized triplet–triplet annihilation. While recent interest in …
Spin statistics for triplet–triplet annihilation upconversion: Exchange coupling, intermolecular orientation, and reverse intersystem crossing
Triplet–triplet annihilation upconversion (TTA-UC) has great potential to significantly
improve the light harvesting capabilities of photovoltaic cells and is also sought after for …
improve the light harvesting capabilities of photovoltaic cells and is also sought after for …
Triplet-pair states in organic semiconductors
Entanglement of states is one of the most surprising and counterintuitive consequences of
quantum mechanics, with potent applications in cryptography and computing. In organic …
quantum mechanics, with potent applications in cryptography and computing. In organic …