Ligands for f-element extraction used in the nuclear fuel cycle

A Leoncini, J Huskens, W Verboom - Chemical Society Reviews, 2017 - pubs.rsc.org
Liquid–liquid extraction is the major technique being applied for the partitioning of f-
elements from nuclear waste. In this review, the recent developments in ligand design …

Removal of chromium from industrial effluents using nanotechnology: a review

S Mitra, A Sarkar, S Sen - Nanotechnology for Environmental Engineering, 2017 - Springer
The presence of chromium in industrial effluents has become a huge problem worldwide as
hexavalent chromium is highly toxic to animals due to its ability to generate reactive oxygen …

A review of novel green adsorbents as a sustainable alternative for the remediation of chromium (VI) from water environments

A Anjum, SA Mazari, Z Hashmi, AS Jatoi, R Abro… - Heliyon, 2023 - cell.com
The presence of heavy metal, chromium (VI), in water environments leads to various
diseases in humans, such as cancer, lung tumors, and allergies. This review comparatively …

The journey traversed in the remediation of hexavalent chromium and the road ahead toward greener alternatives—A perspective

S Kalidhasan, ASK Kumar, V Rajesh… - Coordination Chemistry …, 2016 - Elsevier
The discharge of heavy metals from industrial wastewater beyond the permissible limit
causes serious pollution to the environment. In this regard, chromium that is discharged from …

The effects of structural variations in neutral phosphorus extractants on UO22+ extraction behavior and radiation stability: experimental and theoretical insights

Q Guo, Y Chen, P Zhang, Y Liu, Y Li, Y Yang… - Journal of Molecular …, 2023 - Elsevier
In the present work, the effects of four neutral phosphorus extractants (TBP, TAP, THP,
TEHP) with different molecular structures on the extraction behaviors towards U (Ⅵ) and …

Exploring phosphoryl oxygen basicity in U (VI) complexation: A comparative study from trialkyl phosphate to phosphine oxide

AR Sachin, G Gopakumar, CVSB Rao… - Journal of …, 2024 - Wiley Online Library
The conventional argument that extraction efficiency depends on the “basicity of the
phosphoryl oxygen” is thoroughly examined in this study. The analysis involves studying the …

Solvent extraction studies with some fission product elements from nitric acid media employing tri-iso-amyl phosphate and tri-n-butyl phosphate as extractants

B Sreenivasulu, A Suresh, N Sivaraman… - … of Radioanalytical and …, 2015 - Springer
Tri-iso-amyl phosphate (TiAP) has been identified as an alternate extractant to tri-n-butyl
phosphate (TBP) for the reprocessing of fast reactor fuels. In the present work, extraction …

Synthesis of tailored bis-succinamides and comparison of their extractability for U (VI), Th (IV) and Eu (III)

ZY Yan, QG Huang, L Wang, F Zhang - Separation and Purification …, 2019 - Elsevier
Nine tailored extractants containing bis-succinamide (BisSCA) skeleton have been
synthesized and identified by NMR and HRMS. The extraction of U (VI), Th (IV) and Eu (III) …

Understanding of interfacial tension and interface thickness of liquid/liquid interface at a finite concentration of alkyl phosphate by molecular dynamics simulation

A Das, SM Ali - Journal of Molecular Liquids, 2019 - Elsevier
The Mulliken charge embedded newly developed OPLS force field has been applied for
computation of various structural and dynamical properties of water–dodecane biphasic …

An insight into third-phase formation in the extraction of thorium nitrate by tris(2-methylbutyl) phosphate and tri-n-alkyl phosphates

S Sarkar, A Suresh, N Sivaraman… - Separation Science and …, 2019 - Taylor & Francis
Third phase (TP) formation in the extraction of Th (IV) by tris (2-methylbutyl) phosphate
(T2MBP) from HNO3 media was studied and compared with tri-n-butyl phosphate (TBP) …