Tuning diradical character is an important topic for organic diradicaloids. Herein, we report
the precise borylation enabling structural isomerism as an effective strategy to modulate …

The electronic structure of the bis (dioxolene) bridging ligand-SQ 2 Th 2-is responsive to
metal–ligand magnetic exchange coupling. Comparison of the crystal structure of (NiSQ) 2 …

The nature of the electronic-structure of polyenes, their delocalization features, and potential
diradicaloid characters constitute a fundamental problem in chemistry. To address this …

Bis (dicyanomethylene)-substituted quinoidal π-conjugated systems possess a high electron-
accepting nature and thus have been extensively investigated for application as n-type …

Low-bandgap π-conjugated small molecules have multiple applications. However, it is still a
big challenge to develop such materials because of the scarcity of effective synthetic …

We demonstrate a diradical character-based molecular design for singlet fission using
polycyclic aromatic hydrocarbons, bisanthene derivatives. Two types of chemical …

Three new carbazole-based hole-transporting materials PTCz-9′ Cz, PTCz-3′ TCz, and
PTCz-NTol2 were synthesized, characterized, and examined for the propensity of exciplex …

As influence factors in generating third-order nonlinear optical (NLO) responses, several
parameters, including the length of π-conjugated linkers, donor/acceptor substituents, and …

In view of the experimental observation of (H2) 2@ C70 and (H2O) 2@ C70, it has been
suggested that hydrogen fluoride (HF) dimer can be completely localized within the sub …

The elucidation of new structure–property relationships in π-conjugated molecules bearing
quinoidal moieties is of relevance because of their use in organic electronics applications …