The example of iron-catalyzed cross-electrophile coupling of aryl chlorides with unactivated
alkyl chlorides via an iron/B 2 pin 2 catalytic system has been developed.(Hetero) aryl …

Herein, we report a t-BuONa-promoted method for the site-selective silylation of 2H-
indazoles. In our system, the selective silylation of 2H-indazoles to access silylated 1H …

A novel strategy was developed to generate silyl radicals from silylboronic pinacol esters
(SPEs) through nucleohomolytic substitution of boron with aminyl radicals. We successfully …

The example of iron-catalyzed reductive fluoroalkylalkenylation of unactivated alkenes has
been disclosed, affording the stereodefined homoallylic fluoroalkanes with high efficiency …

A regiodivergent allylation of 1 H-indoles highly selectively at the C3 and N1 positions with β-
acyl allylic sulfides through desulfurative C–C/C–N bond-forming reactions has been …

An efficient cross-electrophile couplings of aryl fluorosulfates with vinyl chlorosilanes by
using nickel as transition metal catalyst and manganese as reductant has been achieved …

Comprehensive Summary The reductive cross‐coupling between C (aryl)—O and Si—Cl
bonds is of much importance as a valuable strategy for the construction of C (aryl)—Si bonds …

有机化学 Page 1 有机化学 Chinese Journal of Organic Chemistry ARTICLE *
Corresponding authors. E-mail: changhonghong@tyut.edu.cn; mengfanhui@tyut.edu.cn; …

The activation of C—S bond plays a crucial role in the preparation of drug molecules, high-
performance polymers and composite materials, as well as in biomedical, environmental …

Abstract Cu (OAc) 2 mediated C (2)-selective d 3-methylthiolation and methylthiolation of
indoles were developed. With the choice of dimethyl sulfoxide (DMSO) as sulfur source and …