Phase transitions among the rotator phases of the normal alkanes: A review

PK Mukherjee - Physics Reports, 2015 - Elsevier
Although the rotator phases of the normal alkanes have been studied for the greater part of
the century, it is only in the last two decades that the experimental and theoretical …

Rotator phases of the normal alkanes: An x‐ray scattering study

EB Sirota, HE King Jr, DM Singer… - The Journal of chemical …, 1993 - pubs.aip.org
We present results of a detailed x‐ray scattering study on the rotator phases of normal
alkanes: CH3–(CH2) n− 2–CH3 (20≤ n≤ 33). We have characterized a new tilted rotator …

Surface freezing in chain molecules: Normal alkanes

BM Ocko, XZ Wu, EB Sirota, SK Sinha, O Gang… - Physical Review E, 1997 - APS
A rare surface freezing phenomenon is observed in molten normal alkanes, using x-ray and
surface tension measurements. An ordered monolayer forms on the surface of the liquid …

[图书][B] Structural electron crystallography

DL Dorset - 1995 - books.google.com
Arbeitshypothesen sind revidierbar, deklarierten Wahrheiten nicht, sie verkalken zum
System; Arbeitshypothesen passen sich den Menschen an, den deklarierten Wahrheiten …

Phase transitions among the rotator phases of the normal alkanes

EB Sirota, DM Singer - The Journal of chemical physics, 1994 - pubs.aip.org
We present the first calorimetric study of the normal alkanes CH3–(CH2) n− 2–CH3 (21≤
n≤ 30) covering the temperature range of the five rotator phases (whose structures were …

On the origin of the hydrophobic water gap: An X-ray reflectivity and MD simulation study

M Mezger, F Sedlmeier, D Horinek… - Journal of the …, 2010 - ACS Publications
The density deficit of water at hydrophobic interfaces, frequently called the hydrophobic gap,
has been the subject of numerous experimental and theoretical studies in the past decade …

Molecular modeling of covalently attached alkyl monolayers on the hydrogen-terminated Si (111) surface

AB Sieval, B van den Hout, H Zuilhof, EJR Sudhölter - Langmuir, 2001 - ACS Publications
The structure of octadecyl monolayers on the H-terminated Si (111) surface is investigated
by molecular modeling simulations, using substitution percentages from 33.3% to 100% of …

Molecular dynamics simulation of the effects of temperature on a dense monolayer of long‐chain molecules

J Hautman, ML Klein - The Journal of chemical physics, 1990 - pubs.aip.org
Molecular dynamics calculations have been used to study the effects of temperature on a
dense monolayer of hydrocarbon molecules. The simulation system consisted of 90 flexible …

Rotator phases in mixtures of n-alkanes

EB Sirota, HEJ King, HH Shao… - The Journal of Physical …, 1995 - ACS Publications
We present an X-ray scattering study of the effect of mixed chain lengths on the plastic-
crystalline rotator phases of n-alkanes. When the width of the distribution is large, as is the …

Remarks Concerning the Relation between Rotator Phases of Bulk n-Alkanes and Those of Langmuir Monolayers of Alkyl-Chain Surfactants on Water

EB Sirota - Langmuir, 1997 - ACS Publications
Substantial advances have recently been made in characterizing the structures and phase
diagrams of Langmuir monolayers of alkyl-chain surfactants on water. These allow detailed …