Opportunities and Challenges in Applying Solid‐State NMR Spectroscopy in Organic Mechanochemistry

IAA Silva, E Bartalucci, C Bolm… - Advanced Materials, 2023 - Wiley Online Library
In recent years it is shown that mechanochemical strategies can be beneficial in directed
conversions of organic compounds. Finding new reactions proved difficult, and due to the …

Mechanochemical tools in the synthesis of organometallic compounds

DV Aleksanyan, VA Kozlov - Mendeleev Communications, 2023 - Elsevier
In response to rising environmental concerns, chemistry is experiencing a considerable
change in both concepts and practices to adopt more efficient and sustainable technologies …

Modulation of the cytotoxic properties of Pd (II) complexes based on functionalized carboxamides featuring labile phosphoryl coordination sites

DV Aleksanyan, AV Konovalov, SG Churusova… - Pharmaceutics, 2023 - mdpi.com
Platinum-based drugs are commonly recognized as a keystone in modern cancer
chemotherapy. However, intrinsic and acquired resistance as well as serious side effects …

N‐alkylation of benzamides/sulfonamides using alcohols via borrowing hydrogen approach by well‐defined Pd (II) pincer complexes

P Anandaraj, R Ramesh - Applied Organometallic Chemistry, 2023 - Wiley Online Library
The development of green, sustainable, and atom‐economical procedure for the
construction of amides via C‐N bond formation is a high priority in synthetic organic …

Pincer–dipeptide and pseudodipeptide conjugates: Synthesis and bioactivity studies

SG Churusova, DV Aleksanyan, EY Rybalkina… - Journal of Inorganic …, 2022 - Elsevier
Following a recent trend on the application of different pincer scaffolds for the development
of new metal-based antitumor agents, in this work, dipeptides and dipeptide surrogates …

Highly efficient preparation of cellulose nanocrystals by mechano-enzymatic hydrolysis: a mechanism study

Q Zhang, Y Chen, W Su - Catalysis Science & Technology, 2023 - pubs.rsc.org
A one-step mechano-enzymatic hydrolysis (MEH) method was developed to prepare
cellulose nanocrystals (CNCs) under liquid-assisted grinding (LAG) conditions. The …

Luminescent Zn Halide Complexes with 2-(2-Aminophenyl) benzothiazole Derivatives

TS Sukhikh, DS Kolybalov, EK Pylova, SN Konchenko - Inorganics, 2022 - mdpi.com
We report a comparative study of coordination behaviour of 2-(2-aminophenyl)
benzothiazole (NH2-pbt) and its phosphorus-containing derivative, α-aminophosphine oxide …

Experimental and computational insights into the direct cyclopalladation of different unsymmetrical, yet closely related pincer ligands with thione sulfur donors

DV Aleksanyan, SG Churusova, EV Dubasova… - Polyhedron, 2023 - Elsevier
A series of three closely related unsymmetrical pincer ligands featuring thione sulfur donors
have been derived from m-thiophosphorylated phenyl isothiocyanate to probe the effect of a …

(Aminoalkyl) diphenylphosphine sulfides: synthesis and application as building blocks in the design of multidentate ligands for cytotoxic Pd (ii) complexes

AV Konovalov, SG Churusova… - Organic & …, 2023 - pubs.rsc.org
Amino-functionalized phosphoryl compounds are among the most useful molecular
scaffolds in medicinal chemistry, while the potential of their thiophosphorylated analogs …

A greener approach towards the synthesis of N-heterocyclic thiones and selones using the mechanochemical technique

S Rangarajan, HS Kunchur, MS Balakrishna - Dalton Transactions, 2022 - pubs.rsc.org
This manuscript describes the synthesis of N-heterocyclic thiones and selones of a variety of
imidazolium salts involving an eco-friendly and solventless ball-milling technique. The …