Conspectus α-Diazocarbonyl compounds serve as nucleophiles, dipoles, carbene
precursors, and rare electrophiles, enabling a vast array of organic transformations under …

The functionalisation of C–H bonds has been an enormous achievement in synthetic
methodology, enabling new retrosynthetic disconnections and affording simple synthetic …

To date,[3+ 2] cycloadditions of diazo esters with alkynes or alkenes have been a robust tool
to generate pyrazoles and pyrazolines. However, methods capable of generating …

Based on the strategy of polarity reversal in the generation of free radicals derived from
diazo compounds, photocatalyzed multicomponent reactions (MCRs) of nitrogen aromatic …

We report a general protocol for the convergent synthesis of 1, 4-dicarbonyl Z-alkenes form
alkynes using α-diazo sulfonium triflate and water. The C═ O, C═ C, and C–H bonds are …

To explore potential chemical space using DNA-encoded library (DEL) technology, the
development of various types of robust DNA-compatible reactions is urgently needed. Diazo …

A visible-light-induced radical gem-iodoallylation of CF3CHN2 was developed under mild
conditions, delivering a variety of α-CF3-substituted homoallylic iodide compounds in …

A photocatalyst-free radical cleavage of α-diazo sulfonium salts has been developed for the
first time. The reaction provides an efficient method for the generation of diazomethyl …

1, 2, 3-Triazine 1-oxides are formed by nitrosyl addition from tert-butyl nitrite to the
vinylogous position of vinyl diazo compounds. This transformation, which is a formal …

We present herein a visible-light-induced [3+ 2] cycloaddition of a hypervalent iodine (III)
reagent with α-ketoacids for the construction of 5-CF3-1, 3, 4-oxadiazoles that are of …