Osmium-free direct syn-dihydroxylation of alkenes

CJR Bataille, TJ Donohoe - Chemical Society Reviews, 2011 - pubs.rsc.org
Numerous synthetic protocols for producing syn-diols from the corresponding alkenes have
been developed and published over recent years. It is the intent of the following tutorial …

Oxido-peroxido molybdenum (VI) complexes in catalytic and stoichiometric oxidations

M Amini, MM Haghdoost, M Bagherzadeh - Coordination Chemistry …, 2013 - Elsevier
This review mainly discusses the application of oxido-peroxido Molybdenum (VI) complexes
as catalysts or mediators in homogeneous or heterogeneous catalytic systems for oxidations …

Metal-free, NHPI catalyzed oxidative cleavage of C–C double bond using molecular oxygen as oxidant

R Lin, F Chen, N Jiao - Organic letters, 2012 - ACS Publications
A metal-free N-hydroxyphthalimide (NHPI) catalyzed aerobic oxidative cleavage of olefins
has been developed. Molecular oxygen is used as the oxidant and reagent for this …

Palladium-catalyzed direct oxidation of alkenes with molecular oxygen: general and practical methods for the preparation of 1, 2-diols, aldehydes, and ketones

A Wang, H Jiang - The Journal of Organic Chemistry, 2010 - ACS Publications
1, 2-Diols, aldehydes, and ketones are important intermediates in chemical synthesis, and
alkenes are possible precursors for 1, 2-diols, aldehydes, and ketones. Herein, novel and …

Vanadium and molybdenum peroxides: synthesis and catalytic activity in oxidation reactions

V Conte, B Floris - Dalton Transactions, 2011 - pubs.rsc.org
Catalysis by transition metal ions in oxidation reactions with hydrogen peroxide and alkyl
hydroperoxides is a leading topic in the pursuit of more sustainable and selective processes …

Eosin Y catalyzed visible light mediated aerobic photo-oxidative cleavage of the C–C double bond of styrenes

AK Singh, R Chawla, LDS Yadav - Tetrahedron Letters, 2015 - Elsevier
A mild, efficient, and metal-free oxidative cleavage of C–C double bond to aldehydes
utilizing eosin Y as an organophotoredox catalyst has been developed. The green aspects …

Iron‐Catalyzed Highly Enantioselective cis‐Dihydroxylation of Trisubstituted Alkenes with Aqueous H2O2

J Wei, L Wu, HX Wang, X Zhang… - Angewandte Chemie …, 2020 - Wiley Online Library
Reliable methods for enantioselective cis‐dihydroxylation of trisubstituted alkenes are
scarce. The iron (II) complex cis‐α‐[FeII (2‐Me2‐BQPN)(OTf) 2], which bears a tetradentate …

Selective oxidation of aromatic primary alcohols to aldehydes using molybdenum acetylide oxo-peroxo complex as catalyst

AV Biradar, MK Dongare, SB Umbarkar - Tetrahedron Letters, 2009 - Elsevier
Selective oxidation of various aromatic alcohols to aldehydes has been carried out with very
high conversion (90%) and selectivity (90%) for aldehydes using cyclopentadienyl …

Catalysts based on porous polyaromatic frameworks for deep oxidative desulfurization of model fuel in biphasic conditions

LA Kulikov, AV Akopyan, PD Polikarpova… - Industrial & …, 2019 - ACS Publications
The first example of an application of porous aromatic frameworks (PAFs) in synthesis of
catalysts for oxidative desulfurization was described. The mesoporous aromatic framework …

Oxidative cleavage of alkenes using an in situ generated iodonium ion with oxone as a terminal oxidant

PP Thottumkara, TK Vinod - Organic Letters, 2010 - ACS Publications
A facile and operationally convenient catalytic procedure for oxidative cleavage of alkenes is
described. In situ formed [hydroxy (4-carboxyphenyl) iodonium] ion, 2, from the oxidation of 4 …