Direct (hetero) arylation polymerization (DHAP) has recently been established as an
environmentally benign method for the preparation of conjugated polymers. This synthetic …

The direct functionalization of C H bonds in organic compounds has recently emerged as a
powerful and ideal method for the formation of carbon–carbon and carbon–heteroatom …

Cross-coupling reactions, which were discovered almost 50 years ago, are widely used in
both industry and academia. Even though cross-coupling reactions now represent mature …

This Perspective presents the fundamental principles, the elementary reactions, the initial
catalytic systems, and the contemporary catalysts that have converted C–H bond …

A synthetic method for the reductive transformation of nitroarenes into ortho-aminated and-
annulated products is reported. The method operates via the exhaustive deoxygenation of …

The site-selective formation of carbonrcarbon bonds through direct functionalizations of
otherwise unreactive carbonrhydrogen bonds constitutes an economically attractive strategy …

The area of transition‐metal‐catalyzed direct arylation through cleavage of C H bonds has
undergone rapid development in recent years, and is becoming an increasingly viable …

The use of coordinating moieties as directing groups for the functionalization of aromatic C
H bonds has become an established tool to enhance reactivity and induce regioselectivity …

The transition-metal-catalyzed functionalization of C− H bonds is a powerful method for
generating carbon− carbon bonds. Although significant advances to this field have been …

We have developed a method for auxiliary-directed, palladium-catalyzed β-arylation and
alkylation of sp3 and sp2 C− H bonds in carboxylic acid derivatives. The method employs a …