Chiral sulfinyl compounds, sulfoxides, sulfoximines, sulfinamides, and other derivatives, play
an important role in asymmetric synthesis as versatile auxiliaries, ligands, and catalysts …

Sulfur can form diverse S (IV) and S (VI) stereogenic centers, of which some have gained
significant attention recently due to their increasing use as pharmacophores in drug …

Direct construction of chiral S (VI) from prochiral S (II) is a formidable challenge due to the
inevitable formation of stable chiral S (IV). Previous synthetic strategies rely on the …

An efficient and metal-free approach for the synthesis of sulfilimines from sulfenamides with
aryne and cyclohexyne precursors has been developed. The reaction proceeds through …

Sulfilimines are valuable compounds both in organic synthesis and in pharmaceuticals.
Here we developed a mild and simplified method for preparation of sulfilimines via selective …

Enantioenriched sulfoxides have found ever-increasing applications in marketed drugs or as
candidates in clinical trials. They are also frequently used as key motifs in chiral ligands or …

Under appropriate conditions, hydrogen peroxide is able to perform a multitude of oxidative
organic reactions in an economically, technically, and environmentally satisfying manner …

In this study, we present a novel and efficient approach for the oxidative esterification of
sulfenamides using phenyliodonium diacetate, enabling the synthesis of sulfinimidate esters …

Optically active sulfoximines are a promising substance in medicinal chemistry. However, a
methodology for preparing chiral sulfoximines in a stereoselective manner has been …

A novel and efficient S-arylation of sulfenamides with diaryliodonium salts for the synthesis
of sulfilimines is developed. The reaction proceeds smoothly under transition-metal-free and …