Recent progress on donor and donor–donor carbenes

D Zhu, L Chen, H Fan, Q Yao, S Zhu - Chemical Society Reviews, 2020 - pubs.rsc.org
Donor and donor–donor carbenes are two important kinds of carbenes, which have
experienced tremendous growth in the past two decades. This review provides a …

Rhodium (III)‐Catalyzed Enantio‐and Diastereoselective C− H Cyclopropylation of N‐Phenoxylsulfonamides: Combined Experimental and Computational Studies

G Zheng, Z Zhou, G Zhu, S Zhai, H Xu… - Angewandte Chemie …, 2020 - Wiley Online Library
Cyclopropane rings are a prominent structural motif in biologically active molecules. Enantio‐
and diastereoselective construction of cyclopropanes through C− H activation of arenes and …

Molybdenum–Quinone-Catalyzed Deoxygenative Coupling of Aromatic Carbonyl Compounds

S Banerjee, T Kobayashi, K Takai, S Asako… - Organic Letters, 2022 - ACS Publications
In the presence of triphenylphosphine as a mild reductant, the use of catalytic amounts of Mo
(CO) 6 and an ortho-quinone ligand enables the intermolecular reductive coupling of …

Molybdenum‐Catalyzed Deoxygenative Cyclopropanation of 1, 2‐Dicarbonyl or Monocarbonyl Compounds

LY Cao, JN Luo, JS Yao, DK Wang… - Angewandte …, 2021 - Wiley Online Library
The transition‐metal‐catalyzed cyclopropanation of alkenes by the decomposition of diazo
compounds is a powerful and straightforward strategy to produce cyclopropanes, but is …

Recent Developments in Isoindole Chemistry

RA Weintraub, X Wang - Synthesis, 2023 - thieme-connect.com
Isoindoles are highly reactive aromatic heterocycles that have a variety of important
applications in areas such as medicine, analytical detection, and solar energy. Due to their …

Electron-rich isolated Pt active sites in ultrafine PtFe3 intermetallic catalyst for efficient alkene hydrosilylation

Y Han, Y Xiong, C Liu, H Zhang, M Zhao, W Chen… - Journal of …, 2021 - Elsevier
Regulating electronic structure of active centres to improve the performance of catalysts has
always been a notable research topic, in which many challenges still need to be solved …

Deoxygenative Insertion of Carbonyl Carbon into a C(sp3)–H Bond: Synthesis of Indolines and Indoles

S Asako, S Ishihara, K Hirata… - Journal of the American …, 2019 - ACS Publications
A simple deoxygenation reagent prepared in situ from commercially available Mo (CO) 6
and ortho-quinone has been developed for the synthesis of indoline and indole derivatives …

Methylenespiro [2.3] hexanes via nickel-catalyzed cyclopropanations with [1.1. 1] Propellane

S Yu, A Noble, RB Bedford… - Journal of the American …, 2019 - ACS Publications
[1.1. 1] Propellane is a highly strained tricyclic hydrocarbon whose reactivity is dominated by
addition reactions across the central inverted bond to provide bicyclo [1.1. 1] pentane …

Silver (I)-Catalyzed Oxidative Cyclopropanation of 1, 6-Enynes: Synthesis of 3-Aza-bicyclo [3.1. 0] hexane Derivatives

X Chen, Z Luo, Y Chen, Y Zhang - Organic Letters, 2022 - ACS Publications
A simple Ag (I)-catalyzed oxidative cyclopropanation of heteroatom-tethered 1, 6-enynes for
the establishment of valuable functionalized 3-aza-bicyclo [3.1. 0] hexane is presented …

Molybdenum‐Catalyzed Deoxygenative Cyclization of Carbonyl Compounds for the Synthesis of Pyrido[2,1‐a]isoindoles

S Asako, T Kobayashi, S Ishihara… - Asian Journal of Organic …, 2021 - Wiley Online Library
Molybdenum‐Catalyzed Deoxygenative Cyclization of Carbonyl Compounds for the Synthesis
of Pyrido[2,1‐a]isoindoles - Asako - 2021 - Asian Journal of Organic Chemistry - Wiley Online …