Origin of High Diastereoselectivity in Reactions of Seven‐Membered‐Ring Enolates
Unlike many reactions of their six‐membered‐ring counterparts, the reactions of chiral seven‐
membered‐ring enolates are highly diastereoselective. Diastereoselectivity was observed …
membered‐ring enolates are highly diastereoselective. Diastereoselectivity was observed …
Brønsted Base‐Catalyzed Formal Reductive [3+ 2] Annulation of 4, 4, 4‐Trifluorocrotonate and α‐Iminoketones
A Kondoh, M Terada - Chemistry–A European Journal, 2021 - Wiley Online Library
Abstract A formal reductive [3+ 2] annulation of 4, 4, 4‐trifluorocrotonate and α‐iminoketones
was developed under Brønsted base catalysis. A single phosphazene base efficiently …
was developed under Brønsted base catalysis. A single phosphazene base efficiently …
Development of the Meyer–Schuster Rearrangement on Propargylic Alcohols with Fluorinated Chains
F Justaud, R Grée - European Journal of Organic Chemistry, 2023 - Wiley Online Library
Abstract The Meyer–Schuster Rearrangement (MSR) is a challenging process for
propargylic alcohols bearing fluorine atom (s) on their chains. Most classical …
propargylic alcohols bearing fluorine atom (s) on their chains. Most classical …