Atomically precise noble metal nanoclusters as efficient catalysts: a bridge between structure and properties

Y Du, H Sheng, D Astruc, M Zhu - Chemical reviews, 2019 - ACS Publications
Improving the knowledge of the relationship between structure and properties is
fundamental in catalysis. Recently, researchers have developed a variety of well-controlled …

Atomically precise colloidal metal nanoclusters and nanoparticles: fundamentals and opportunities

R Jin, C Zeng, M Zhou, Y Chen - Chemical reviews, 2016 - ACS Publications
Colloidal nanoparticles are being intensely pursued in current nanoscience research.
Nanochemists are often frustrated by the well-known fact that no two nanoparticles are the …

Unraveling the impact of gold (I)–thiolate motifs on the aggregation‐induced emission of gold nanoclusters

Z Wu, Q Yao, OJH Chai, N Ding, W Xu… - Angewandte …, 2020 - Wiley Online Library
Aggregation‐induced emission (AIE) provides an efficient strategy to synthesize highly
luminescent metal nanoclusters (NCs), however, rational control of emission energy and …

Gold nanoclusters for theranostic applications

Y Zheng, J Wu, H Jiang, X Wang - Coordination Chemistry Reviews, 2021 - Elsevier
Gold nanoclusters, consisting of a few to several hundred Au atoms with a core size below 2
nm, have attracted worldwide attention in the biomedicine because of their supernormal …

Au 25 (SR) 18: the captain of the great nanocluster ship

X Kang, H Chong, M Zhu - Nanoscale, 2018 - pubs.rsc.org
Noble metal nanoclusters are in the intermediate state between discrete atoms and
plasmonic nanoparticles and are of significance due to their atomically accurate structures …

Molecular reactivity of thiolate-protected noble metal nanoclusters: synthesis, self-assembly, and applications

Q Yao, Z Wu, Z Liu, Y Lin, X Yuan, J Xie - Chemical Science, 2021 - pubs.rsc.org
Thiolate-protected noble metal (eg, Au and Ag) nanoclusters (NCs) are ultra-small particles
with a core size of less than 3 nm. Due to the strong quantum confinement effects and …

Electronic and geometric structure, optical properties, and excited state behavior in atomically precise thiolate-stabilized noble metal nanoclusters

CM Aikens - Accounts of Chemical Research, 2018 - ACS Publications
Conspectus Ligand-protected noble metal nanoclusters are of interest for their potential
applications in areas such as bioimaging, catalysis, photocatalysis, and solar energy …

Three-orders-of-magnitude variation of carrier lifetimes with crystal phase of gold nanoclusters

M Zhou, T Higaki, G Hu, MY Sfeir, Y Chen, D Jiang… - Science, 2019 - science.org
We report a three-orders-of-magnitude variation of carrier lifetimes in exotic crystalline
phases of gold nanoclusters (NCs) in addition to the well-known face-centered cubic …

Stabilizing ultrasmall Au clusters for enhanced photoredox catalysis

B Weng, KQ Lu, Z Tang, HM Chen, YJ Xu - Nature communications, 2018 - nature.com
Recently, loading ligand-protected gold (Au) clusters as visible light photosensitizers onto
various supports for photoredox catalysis has attracted considerable attention. However, the …

Understanding seed-mediated growth of gold nanoclusters at molecular level

Q Yao, X Yuan, V Fung, Y Yu, DT Leong… - Nature …, 2017 - nature.com
The continuous development of total synthesis chemistry has allowed many organic and
biomolecules to be produced with known synthetic history–that is, a complete set of step …