The chemistry of the p-block elements is a huge playground for fundamental and applied
work. With their bonding from electron deficient to hypercoordinate and formally hypervalent …

An important role in organometallic chemistry is predicted for N‐heterocyclic carbenes,
which are no longer laboratory curiosites but have developed into an industrially interesting …

The Lewis-acid/base reaction between a ligand and a metal fragment to form a complex is
one of the fundamental chemical reactions. In accord with their role as Lewis-bases, most …

Quasi-Thermoneutral P → B Interactions within Di- and Tri-Phosphine Boranes | Inorganic
Chemistry ACS ACS Publications C&EN CAS Find my institution Log In Inorganic Chemistry …

The ionic chlorophosphane [L′ P]+ Cl−(1) was obtained for the ligand L′= N, N′-bis (tert-
butyl)-1, 4-diaza-2-butene. By contrast, the CC-saturated analog LP-Cl (2, L= N, N′-bis (tert …

An in situ redox method is employed to prepare N-heterocyclic bromophosphines in good
yield and purity. Such bromophosphines may be treated with a variety of bromide …

The activation of relatively inert E–X σ-bonds by low-valent main group metal complexes is
receiving increasing interest. We here confirm the promising potential of gallanediyl LGa (L …

Cyclic phosphenium (1a) and arsenium (1b) cations are formed either by treatment of
germylene 2b with ECl3 (E= P, As) or via the metathetical reaction of LiN (But) CCN (But) Li …

The aromatic stabilization of cyclic phosphenium cations (general type C2N2P+) was
studied by experimental methods (synthesis, multinuclear NMR, single crystal X‐ray …

Abstract Lange Zeit war die Chemie der N‐heterocyclischen Carbene auf
Koordinationsverbindungen beschränkt, die aus Azoliumsalz‐Vorstufen synthetisiert werden …