The engineering of conjugated acetylenic polymers (CAPs) has great potential for
photosensitized oxyanion activation, wherein their catalytic performance can be further …

A rhodium‐based multicomponent catalytic system for well‐controlled living polymerization
of phenylacetylenes has been developed. The catalytic system is composed of readily …

Various α, β-unsaturated carbonyl compounds, such as acrylates and acrylamides, were
quantitatively introduced to the terminal chain end of poly (phenylacetylene) s by C–C bond …

A series of neutral [RhX (nbd)(κC-MeIm∩ Z)] and cationic [Rh (nbd)(κ2C, N-MeIm∩ Z)]+(X=
Cl, Br; MeIm= 3-methylimidazol-2-yliden-1-yl;∩ Z= N-functionalized wingtip; nbd= 2, 5 …

This work reports the functionalization of azide–alkyne click-based microporous organic
polymer (CMOP). The generation of triazolium salts and successive deprotonation induced …

Well‐controlled living polymerization of water‐soluble phenylacetylene derivatives in water
was achieved for the first time using a multicomponent catalytic system consisting of [Rh …

Unique bench‐stable rhodium (I) complexes bearing an aryl‐substituted 1, 3, 5‐hexatriene
chain have been synthesized by reactions of (bicyclo [2.2. 1] hepta‐2, 5‐diene) rhodium (I) …

The cationic compound [Rh (nbd){κ2P, N-Ph2P (CH2) 3NMe2}][BF4] efficiently catalyzes the
polymerization of a series of ring-substituted phenylacetylene derivatives, R-C6H4–CCH …

A substantially improved method for living polymerization of N‐propargylamides and their
derivatives has been developed. Rhodium (I) complexes bearing an aryl‐substituted 1, 3, 5 …

The alkynyl [Rh (CC-Ph)(nbd){Ph2P (CH2) 3Z} 2] and [Rh (CC-Ph)(cod){Ph2P (CH2)
3Z}](cod= 1, 5-cyclooctadiene, nbd= 2, 5-norbornadiene) and methyl complexes [Rh …