[HTML][HTML] Photophysical properties of lumichromes in water

M Sikorski, E Sikorska, A Koziolowa, RG Moreno… - … of Photochemistry and …, 2001 - Elsevier
The photophysics of lumichrome, 1-methyllumichrome, and lumiflavin in water solutions
have been investigated. Fluorescence lifetimes of 2.7 and 2.2 ns were observed for …

Fluorescence solvatochromism in lumichrome and excited-state tautomerization: a combined experimental and DFT study

NS Moyon, S Mitra - The Journal of Physical Chemistry A, 2011 - ACS Publications
Fluorescence solvatochromism of lumichrome (LC) was studied by steady-state and time-
resolved fluorescence spectroscopy. The excited-state properties of LC do not show any …

Efficiency of singlet oxygen generation by alloxazines and isoalloxazines

E Sikorska, M Sikorski, RP Steer, F Wilkinson… - Journal of the …, 1998 - pubs.rsc.org
Some spectroscopic properties of alloxazines and the lifetimes of their singlet and triplet
states in acetonitrile are reported. In addition, the efficiencies of singlet oxygen production by …

Spectroscopy and photophysics of iso-and alloxazines: experimental and theoretical study

E Sikorska, IV Khmelinskii, DR Worrall, J Koput… - Journal of …, 2004 - Springer
We present a systematic study of the effect of methyl substitution on iso-and alloxazines in
acetonitrile solutions. Substitution patterns have profound effects on both spectral and …

Photochemistry of riboflavin derivatives in methanolic solutions

M Insińska-Rak, A Golczak… - The Journal of Physical …, 2012 - ACS Publications
Light-induced degradation of the riboflavin derivatives is reported, including 5-deaza-
riboflavin, iso-6, 7-riboflavin, 3-methyl-tetra-acetyl-riboflavin (3MeTARF), and 3-benzyl …

Bicomponent hydrogels of lumichrome and melamine: photoluminescence property and its dependency on pH and temperature

P Bairi, B Roy, AK Nandi - The Journal of Physical Chemistry B, 2010 - ACS Publications
Lumichrome (L) and melamine (M) produce thermoreversible hydrogels in LM31 and LM11
compositions, but LM13 composition does not produce hydrogel (the numbers indicate the …

The photophysics of alloxazine: a quantum chemical investigation in vacuum and solution

S Salzmann, CM Marian - Photochemical & Photobiological Sciences, 2009 - pubs.rsc.org
(Time-dependent) Kohn–Sham density functional theory and a combined density
functional/multi-reference configuration interaction method (DFT/MRCI) were employed to …

Theoretical analysis of the electron spin density distribution of the flavin semiquinone isoalloxazine ring within model protein environments

JI García, M Medina, J Sancho, PJ Alonso… - The Journal of …, 2002 - ACS Publications
Flavin cofactors are essential for the biological function of many electron-transfer proteins.
The electron spin density distribution in the semiquinone (radical) state of the flavin ring has …

QM/MM Study on mechanistic photophysics of alloxazine chromophore in aqueous solution

XP Chang, XY Xie, SY Lin, G Cui - The Journal of Physical …, 2016 - ACS Publications
Compared with isoalloxazine, the core chromophore of biologically important flavins,
alloxazine exhibits much lower fluorescence quantum yield and larger intersystem-crossing …

Photophysical properties of N-methyl and N-acetyl substituted alloxazines: a theoretical investigation

H Guo, X Ma, Z Lei, Y Qiu, J Zhao, B Dick - Physical Chemistry …, 2021 - pubs.rsc.org
The electronic structure and photophysical properties of a series of N-methyl and N-acetyl
substituted alloxazines (AZs) were investigated with extensive density functional theory …