Si–B reagents, namely silylboronic esters and silylboranes, have become increasingly
attractive as versatile reagents to introduce silicon and boron atoms into organic …

Alkenes bearing four carbon-based groups are ubiquitous motifs in chemical sciences due
to their various applications from medicinal to materials chemistry, and as chemical …

We report a phosphine-catalyzed trans hydroboration of alkynoate esters and amides. The
reaction proceeds under mild conditions with exclusive (E)-selectivity to afford (E)-β-boryl …

We report a combined experimental and computational study of Pd/Senphos-catalyzed
carboboration of 1, 3-enynes utilizing DFT calculations, 31P NMR study, kinetic study …

A new family of carbon‐bound boron enolates, generated by a kinetically controlled halogen
exchange between chlorocatecholborane and silylketene acetals, is described. These C …

A copper-catalyzed highly regio-and stereoselective silaboration of alkynes was developed.
In this work, direct cis-difunctionalization of alkynes was realized with silaboronate reagent …

We report the first trans phosphinoboration of internal alkynes. With an organophosphine
catalyst, alkynoate esters and the phosphinoboronate Ph2P‐Bpin are efficiently converted …

The hydroboration of alkynes with bis (pinacolato) diboron (B2pin2) using H2O or untreated
H2O as a solvent is a challenging task. This work reports the aqueous N-heterocyclic …

The synthesis of organoboron compounds have attracted the attention of the synthetic
community. In particular, molecules with C (sp2)‐B bonds enable the transformation to new …

We have achieved the first anti‐borylstannylation of alkynes by using (o‐
phenylenediaminato) borylstannanes. This reaction afforded 1‐boryl‐2‐stannylalkenes with …