Recent advances in liquid hydrosilane-mediated catalytic N-formylation of amines with CO 2
Carbon dioxide is an ideal raw material for the synthesis of complex organic compounds
because of its rich, non-toxic, and good physical properties. It is of great significance to …
because of its rich, non-toxic, and good physical properties. It is of great significance to …
Effective Formylation of Amines with Carbon Dioxide and Diphenylsilane Catalyzed by Chelating bis(tzNHC) Rhodium Complexes
TVQ Nguyen, WJ Yoo, S Kobayashi - Angewandte Chemie, 2015 - Wiley Online Library
The reductive formylation of amines using CO2 and hydrosilanes is an attractive method for
incorporating CO2 into valuable organic compounds. However, previous systems required …
incorporating CO2 into valuable organic compounds. However, previous systems required …
Monoanionic NSiN-type ligands in transition metal coordination chemistry and catalysis
FJ Fernández-Alvarez, R Lalrempuia, LA Oro - Coordination Chemistry …, 2017 - Elsevier
The number of late transition metal complexes bearing tridentate monoanionic silyl-based
NSiN-type ligands has grown in the last few years. This review describes the synthetic …
NSiN-type ligands has grown in the last few years. This review describes the synthetic …
Bis (1, 2, 3-triazol-5-ylidenes)(i-bitz) as stable 1, 4-bidentate ligands based on mesoionic carbenes (MICs)
G Guisado-Barrios, J Bouffard, B Donnadieu… - …, 2011 - ACS Publications
Direct metalation of bis (1, 2, 3-triazolium) salts affords mononuclear rhodium (I) complexes,
which feature a 1, 4-bidentate bis (1, 2, 3-triazol-5-ylidene)(i-bitz) ligand. The topology of the …
which feature a 1, 4-bidentate bis (1, 2, 3-triazol-5-ylidene)(i-bitz) ligand. The topology of the …
Hydrosilylation with biscarbene Rh (I) complexes: experimental evidence for a silylene-based mechanism
P Gigler, B Bechlars, WA Herrmann… - Journal of the American …, 2011 - ACS Publications
A detailed study investigating the mechanism of the hydrosilylation of 4-F-acetophenone by
N-heterocyclic biscarbene rhodium (I) complexes was performed, delivering substantial …
N-heterocyclic biscarbene rhodium (I) complexes was performed, delivering substantial …
“Dynamical Docking” of Cyclic Dinuclear Au (I) Bis-N-heterocyclic Complexes Facilitates Their Binding to G-Quadruplexes
With the aim to improve the design of metal complexes as stabilizers of noncanonical DNA
secondary structures, namely, G-quadruplexes (G4s), a series of cyclic dinuclear Au (I) N …
secondary structures, namely, G-quadruplexes (G4s), a series of cyclic dinuclear Au (I) N …
Charged Hole‐Transporting Materials Based on Imidazolium for Defect Passivation in Inverted Perovskite Solar Cells
YS Tingare, MC Li, SH Teng, JH Lin, C Su, SJ Lin… - Solar …, 2024 - Wiley Online Library
The hole‐transporting material (HTM) in perovskite solar cells (PSCs) provides an ideal
interface with the perovskite layer for hole collection while influencing the perovskite …
interface with the perovskite layer for hole collection while influencing the perovskite …
Preparation of phosphorescent iridium (III) complexes with a dianionic C, C, C, C-tetradentate ligand
MA Esteruelas, AM López, E Oñate… - Inorganic …, 2018 - ACS Publications
The preparation and photophysical properties of heteroleptic iridium (III) complexes
containing a dianionic C, C, C, C-tetradentate ligand and a cyclometalated phenylpyridine …
containing a dianionic C, C, C, C-tetradentate ligand and a cyclometalated phenylpyridine …
Accessing a Biologically Relevant Benzofuran Skeleton by a One-Pot Tandem Heck Alkynylation/Cyclization Reaction Using Well-Defined Palladium N-Heterocyclic …
Well-defined palladium N-heterocyclic carbene (NHC) complexes were employed in the one-
pot tandem Heck alkynylation/cyclization sequence for preparing biologically relevant …
pot tandem Heck alkynylation/cyclization sequence for preparing biologically relevant …
Synthesis and comparative study of the anticancer activity of η3-allyl palladium (II) complexes bearing N-heterocyclic carbenes as ancillary ligands
T Scattolin, E Bortolamiol, I Caligiuri, F Rizzolio… - Polyhedron, 2020 - Elsevier
In this paper we report the synthesis and characterization (NMR, IR, elemental analysis and
XRD) of fifteen new Pd (II) allyl complexes containing at least one N-heterocyclic carbene …
XRD) of fifteen new Pd (II) allyl complexes containing at least one N-heterocyclic carbene …